Study of Hydrolysis of Nitrile Derivatives of closo-Dodecaborate Anion (Et4N)[B12H11N≡C–R] (R = Me, Et, nPr, iPr)

A. V. Nelyubin; Нелюбин А. В.; I. N. Klyukin; Клюкин И. Н.; N. A. Selivanov; Селиванов Н. А.; A. Yu. Bykov; Быков А. Ю.; A. S. Kubasov; Кубасов А. С.; A. P. Zhdanov; Жданов А. П.; K. Yu. Zhizhin; Жижин К. Ю.; N. T. Kuznetsov; Кузнецов Н. Т.

doi:10.31857/S0044457X22602310

Study of Hydrolysis of Nitrile Derivatives of closo-Dodecaborate Anion (Et4N)[B12H11N≡C–R] (R = Me, Et, nPr, iPr)

Authors: Nelyubin A.V.¹, Klyukin I.N.¹, Selivanov N.A.¹, Bykov A.Y.¹, Kubasov A.S.¹, Zhdanov A.P.¹, Zhizhin K.Y.¹, Kuznetsov N.T.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Issue: Vol 68, No 6 (2023)
Pages: 768-773
Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://rjmseer.com/0044-457X/article/view/665241
DOI: https://doi.org/10.31857/S0044457X22602310
EDN: https://elibrary.ru/UFEDHV
ID: 665241

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Abstract

The reaction of nitrile derivatives of closo-dodecaborate anion (Et4N)[B12H11N≡C–R] (R = Me, Et, nPr, iPr) with water has yielded a series of (Et4N)[B12H11NH=C(OH)–R] iminols. It has been demonstrated that the hydrolysis products are in acid–base iminol–amide equilibrium, which can be controlled by changing the pH of a medium. The reaction products have been identified by 11В, 1Н, 13С NMR, IR spectroscopy, and ESI mass spectrometry. The structures of the [B12H11(Z-NH=C(OH)nC3H7)]− and [B12H11(E-NH–C(O)nC3H7)]2− anions have been determined by X-ray single-crystal diffraction.

Keywords

closo-dodecaborates, nitrile derivatives, iminols, amides

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