Synthesis and Functionalization of Unsymmetrical Terbium(III) Bis-Phthalocyaninates, Promising Components of Hybrid Magnetic Materials

A. V. Yagodin; Ягодин А. В.; I. D. Kormshchikov; Кормщиков И. Д.; A. G. Martynov; Мартынов А. Г.; Yu. G. Gorbunova; Горбунова Ю. Г.; A. Yu. Tsivadze; Цивадзе А. Ю.

doi:10.31857/S0044457X23600706

Synthesis and Functionalization of Unsymmetrical Terbium(III) Bis-Phthalocyaninates, Promising Components of Hybrid Magnetic Materials

Authors: Yagodin A.V.¹, Kormshchikov I.D.², Martynov A.G.¹, Gorbunova Y.G.¹^,3, Tsivadze A.Y.¹^,3
Affiliations:
1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
2. Faculty of Chemistry, Moscow State University
3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Issue: Vol 68, No 9 (2023)
Pages: 1146-1153
Section: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://rjmseer.com/0044-457X/article/view/666208
DOI: https://doi.org/10.31857/S0044457X23600706
EDN: https://elibrary.ru/WRKOIB
ID: 666208

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Abstract

A new unsymmetrical terbium bis-Phthalocyaninate Tb(A7B) with one terminal aliphatic OH group was obtained by template cross-condensation of diethoxyphthalonitrile (A) and phthalonitrile (B) functionalized with diethylene glycol moiety. The subsequent functionalization of the complex included the successive replacement of this OH group by the iodide and thioacetate substituents. The synthesized complexes can act as components of hybrid materials upon immobilization on surfaces of various nature.

Keywords

phthalocyanine, double-decker complex, terbium, anchor groups, molecular magnetism, hybrid materials

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