Crystal structures and properties of metal-organic coordination polymers of the [Zn2(BDC)X (BDC-I)(2–X)DABCO] series

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Abstract

New mixed-ligand organometallic coordination polymers based on zinc terephthalate (bdc), 2-iodoterephthalate (bdc-I) and 1,4-diazabicyclo[2.2.2]octane (dabco) were obtained: [Zn2(bdc)1.67(bdc-I)0.33dabco] (I), [Zn2(bdc)1.46(bdc-I)0.54dabco] (II), [Zn2(bdc)1.12(bdc-I)0.88dabco] (III), [Zn2(bdc)0.80(bdc-I)1.2dabco] (IV), [Zn2(bdc)0.46(bdc-I)1.54dabco] (V). Their structure and composition were determined by X-ray diffraction, X-ray phase, and elemental analysis. Compounds I–V are isostructural with [Zn2(bdc)2(dabco)], but not with [Zn2(bdc-I)2(dabco)], which we have not described previously, which is confirmed by X-ray phase analysis data. Experiments on the sorption of diiodine vapors are consistent with the idea that the presence of a larger amount of 2-iodoterephthalate in the MOF should lead to a decrease in pore volume: the greatest amount of I2 is absorbed by I, and the smallest by V.

About the authors

A. S. Zaguzin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: zaguzin@niic.nsc.ru
Academician Lavrentiev Avenue 3, Novosibirsk, 630090 Russia

Y. A. Zaitsev

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State Technical University

Email: zaguzin@niic.nsc.ru
Academician Lavrentiev Avenue 3, Novosibirsk, 630090 Russia; Karl Marx Avenue 20, Novosibirsk, 630073 Russia

A. V. Zaitsev

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University

Email: zaguzin@niic.nsc.ru
Academician Lavrentiev Avenue 3, Novosibirsk, 630090 Russia; Pirogova 1, Novosibirsk, 630090 Russia

N. A. Korobeynikov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: zaguzin@niic.nsc.ru
Academician Lavrentiev Avenue 3, Novosibirsk, 630090 Russia

M. A. Bondarenko

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: zaguzin@niic.nsc.ru
Academician Lavrentiev Avenue 3, Novosibirsk, 630090 Russia

E. A. Maksimovskii

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: zaguzin@niic.nsc.ru
Academician Lavrentiev Avenue 3, Novosibirsk, 630090 Russia

V. P. Fedin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: zaguzin@niic.nsc.ru
Academician Lavrentiev Avenue 3, Novosibirsk, 630090 Russia

S. A. Adonin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Favorsky Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

Author for correspondence.
Email: zaguzin@niic.nsc.ru
Academician Lavrentiev Avenue 3, Novosibirsk, 630090 Russia; Favorsky 1, Irkutsk, 664033 Russia

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