Framework tetrarhodanomercurate complexes of Mn(II), Fe(II), Cd(II) with nicotinamide: synthesis and crystal structure

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详细

New bimetallic complexes of the composition [MHg(C6H6N2O)2 (SCN)4] have been synthesized, where M = Mn (I), Fe (II), Cd (III); C6H6N2O is nicotinamide (NA). The compounds were obtained from aqueous solutions and studied by CHNS/O analysis, IR spectroscopy, inductively coupled plasma optical emission spectrometry (ICP-OES) and X-ray diffraction analysis (XRD). Compounds I–III are isostructural and crystallize in the monoclinic syngony (space group C2/c). The coordination environment of the M atom is formed by two donor nitrogen atoms of two monodentately coordinated NA and four nitrogen atoms of the SCN groups, which form bridges between the M2+ and Hg2+ ions, connecting them into a three-dimensional framework. Hg2+ ions have a tetrahedral coordination environment consisting of four S atoms of four SCN groups.

作者简介

D. Barantsev

Kuzbass State Technical University named after T.F. Gorbachev

Email: ctg.htnv@kuzstu.ru
Kemerovo, 650000 Russia

N. Pervukhina

Nikolaev Institute of Inorganic Chemistry of SB RAS (NIIC SB RAS)

Email: ctg.htnv@kuzstu.ru
Novosibirsk, 630092 Russia

N. Kuratieva

Nikolaev Institute of Inorganic Chemistry of SB RAS (NIIC SB RAS)

Email: ctg.htnv@kuzstu.ru
Novosibirsk, 630092 Russia

T. Cherkasova

Kuzbass State Technical University named after T.F. Gorbachev

编辑信件的主要联系方式.
Email: ctg.htnv@kuzstu.ru
Kemerovo, 650000 Russia

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