Solid Solution in the Pseudobinary System Ba2YMoO6–[Ba2YCuO5]

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Samples of the pseudobinary system Ba2YMoO6–[Ba2YCuO5] were synthesized using the gel combustion method. The obtained samples were studied by X-ray diffraction and photoluminescence spectroscopy. By replacing Mo with Cu, it was possible to stabilize the cubic phases Fm3¯m and F4¯3m of the Ba2YMo1–xCuxO6–δ solid solution (0 ≤ x ≤ 0.5) in air.

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作者简介

M. Smirnova

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

编辑信件的主要联系方式.
Email: smirnova_macha1989@mail.ru
俄罗斯联邦, Moscow, 119991

M. Kopyeva

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: smirnova_macha1989@mail.ru
俄罗斯联邦, Moscow, 119991

G. Nipan

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: smirnova_macha1989@mail.ru
俄罗斯联邦, Moscow, 119991

G. Nikiforova

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: smirnova_macha1989@mail.ru
俄罗斯联邦, Moscow, 119991

E. Tekshina

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: smirnova_macha1989@mail.ru
俄罗斯联邦, Moscow, 119991

A. Arkhipenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: smirnova_macha1989@mail.ru
俄罗斯联邦, Moscow, 119991

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2. Fig. 1. Investigated compositions in the concentration triangle of the Ba2Y2O5-BaMoO4-BaCuO2 system.

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3. Fig. 2. Diffractograms of samples of Ba2YMo1-xCuxO6-δ system (0 ≤ x ≤ 0.5) at x = 0 (1), 0.1 (2), 0.2 (3), 0.25 (4), 0.33 (5), 0.5 (6).

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4. Fig. 3. Dependence of the unit cell volume of Fm3m and F43m phases on the copper content (x) in Ba2YMo1-xCuxO6-δ samples (0 ≤ x ≤ 0.5).

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5. Fig. 4. Exciton (1) and emission (2) spectra of the Ba2YCu0.5Mo0.5O6-δ sample.

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