A study of the impact of the initial reagent’s chemical nature on the mechanochemical synthesis of silver-substituted hydroxyapatite

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Resumo

Samples of hydroxyapatite with the substitution of calcium ions for silver ions were obtained by the mechanochemical method using silver nitrate and silver phosphate substituent ions as sources. The samples were characterised using X-ray diffraction and FTIR spectroscopy. It was observed that the use of AgNO3 resulted in the presence of residual nitrate in the synthesis products. Conversely, the use of Ag3PO4 enabled the obtaining of single-phase silver-substituted carbonate-hydroxyapatite. The introduction of silver cations in the position of calcium cations was found to increase the parameters of the hydroxyapatite crystal lattice.

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Sobre autores

S. Makarova

Institute of State Chemistry and Mechanochemistry SB RAS

Autor responsável pela correspondência
Email: makarova@solid.nsc.ru
Rússia, Novosibirsk, 630090

I. Borodulina

Institute of State Chemistry and Mechanochemistry SB RAS

Email: makarova@solid.nsc.ru
Rússia, Novosibirsk, 630090

N. Eremina

Institute of State Chemistry and Mechanochemistry SB RAS

Email: makarova@solid.nsc.ru
Rússia, Novosibirsk, 630090

I. Prosanov

Institute of State Chemistry and Mechanochemistry SB RAS

Email: makarova@solid.nsc.ru
Rússia, Novosibirsk, 630090

N. Bulina

Institute of State Chemistry and Mechanochemistry SB RAS

Email: makarova@solid.nsc.ru
Rússia, Novosibirsk, 630090

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2. Fig. 1. Variation of diffractograms (a) and IR spectra (b) of samples of composition corresponding to reaction (1) at x = 1 during mechanochemical synthesis. The unmarked reflections refer to the HA phase.

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3. Fig. 2. Variation of diffractograms (a) and IR spectra (b) of samples of composition corresponding to reaction (2) at x = 1 during mechanochemical synthesis. The unmarked reflections refer to the GA phase.

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4. Fig. 3. Variation of unit cell parameters a (a) and c (b), its volume (c) and ROC (d) for the HA phase as a function of the time of mechanochemical treatment of samples of composition corresponding to reactions (1) and (2) at x = 1.

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5. Fig. 4. Diffractograms (a) and IR spectra (b) of Ag-HA samples synthesized with different degrees of substitution x using Ag3PO4 (reaction (1)). The duration of synthesis is 30 min.

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6. Fig. 5. Diffractograms (a) and IR spectra (b) of Ag-HA samples synthesized with different degrees of x substitution using AgNO3 (reaction (2)). The duration of synthesis is 30 min.

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7. Fig. 6. Variation of a (a) and c (b) unit cell parameters of the Ag-GA phase, as well as ROC (c) using different sources of silver cations. The data for Ag2O are taken from [18].

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8. Fig. 7. IR spectra (a) and diffractograms (b) of Ag-HA samples synthesized by reaction (1) after washing compared to the spectrum of unsubstituted HA.

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