Aerosol printing of electrochromic films based on nickel and tungsten doped V2O5

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Resumo

Vanadium(V) oxide films doped with 10 mol% NiO and 10 mol. % WO3 were obtained by aerosol printing. In the first case, the film crystallizes in tetragonal β-V2O5 modification with high texturing along the {200} crystallographic plane, while the material is X-ray amorphous when doped with tungsten. At nickel doping the film is formed by one-dimensional structures, while in the case of the sample V2O5–10 mol. % WO3 — by particles of irregular shape or close to rounded. The values of electron yield work from the surface of the materials indicate high defectivity of the film containing WO3. Both samples demonstrate anodic electrochromism, but V2O5–10 mol. % NiO is characterized by higher values of optical contrast and coloring efficiency. The results of the study clearly reflect the influence of the nature of the considered dopants on the functional properties of the obtained materials and demonstrate the promising potential of the aerosol printing method for the formation of electrochromic films.

Sobre autores

P. Gorobtsov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: phigoros@gmail.com
Leninsky pr., 31, Moscow, 119991 Russia

N. Fisenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: phigoros@gmail.com
Leninsky pr., 31, Moscow, 119991 Russia

N. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: phigoros@gmail.com
Leninsky pr., 31, Moscow, 119991 Russia

T. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: phigoros@gmail.com
Leninsky pr., 31, Moscow, 119991 Russia

E. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Autor responsável pela correspondência
Email: phigoros@gmail.com
Leninsky pr., 31, Moscow, 119991 Russia

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