Effect of Water on the Structure of Polyethylene–Polylactide Binary Blends and Polyethylene–Polylactide–Aged Polyethylene Ternary Blends

M. V. Podzorova; Подзорова М. В.; Yu. V. Tertyshnaya; Тертышная Ю. В.; A. V. Khramkova; Храмкова А. В.

doi:10.31857/S0207401X23010090

Effect of Water on the Structure of Polyethylene–Polylactide Binary Blends and Polyethylene–Polylactide–Aged Polyethylene Ternary Blends

作者: Podzorova M.V.¹^,2, Tertyshnaya Y.V.¹^,2, Khramkova A.V.³
隶属关系:
1. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia
2. Plekhanov Russian University of Economics, Moscow, Russia
3. Politecnico di Milano, Piazza Leonardo da Vinci, Milan, Italy
期: 卷 42, 编号 1 (2023)
页面: 35-42
栏目: Chemical physics of polymeric materials
URL: https://rjmseer.com/0207-401X/article/view/674912
DOI: https://doi.org/10.31857/S0207401X23010090
EDN: https://elibrary.ru/HNFZGH
ID: 674912

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详细

The effect of water on double and triple polyethylene (PE)–polylactide (PLA) blends of various compositions, including those with the addition of aged polyethylene as an analog of recycled polymer is studied in this paper. It is established that the composition of the blends directly affects its characteristics, especially when exposed to water as an aggressive factor. PE–PLA composites have a maximum degree of water absorption of about 7.5%, and in the presence of the third component, oxidized polyethylene in the amount of 40 and 50 wt %, the degree of water absorption increases to 10%. It is shown by IR spectroscopy that after the action of water, structural elements belonging to PLA are destroyed, which is due to the more active interaction of water molecules with PLA molecules, while the characteristics of the polyethylene matrix remain practically unchanged.

关键词

polymer blends, polylactide, low density polyethylene, aged polyethylene, hydrolytic degradation

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