Prediction of the thermal-physical properties of amorphous nickel alloys Ni2B, Ni44Nb56, Ni62Nb38 according to component data

Мұқаба

Дәйексөз келтіру

Толық мәтін

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Аннотация

The replacement of traditional materials with amorphous alloys and the operation of products made from them are determined by the structural, temporal and temperature stability of disordered environments. In particular, the thermal stability of an amorphous alloy directly depends on its thermophysical characteristics. Therefore, the article demonstrates the applicability of the rule of mixing components and the use of their data on thermophysical properties in the crystalline state to evaluate similar characteristics of alloys from the metal – metalloid and transition metal – transition metal groups in the amorphous phase. It has been established that for the transition metal – transition metal group, the assessment of the heat capacity of amorphous nickel alloys gives a better approximation to the experimentally established values than for an alloy from the metal – metalloid group. The reasons for the discrepancy between the assessment and experimental data for an alloy from the metal – metalloid group are possibly the covalency of the atomic bonds in contrast to the metallic bond for alloys from the transition metal – transition metal group, the smaller size of the metalloid atoms, its greater mobility and the effect on the refinement of alloy grains. The possibility of an amorphous alloy inheriting some properties of one of the components is indicated, which requires experimental verification.

Толық мәтін

Рұқсат жабық

Авторлар туралы

S. Terekhov

Donetsk Institute of Physics and Technology A.A. Galkina

Хат алмасуға жауапты Автор.
Email: svlter@yandex.ru
Ресей, Donetsk

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2. Fig. 1. Temperature dependence of the heat capacity of crystalline boron B (a; o ‒ data [1], ♦ ‒ [2]) and estimates (----) of the behavior of the heat capacities of Ni2B (b; Δ ‒ [4]), Ni44Nb56 alloys (1; □ ‒ [5]), Ni62Nb38 (2; ▲‒ [5]) in and Ni0.333Zr0.667 [9] (g; ● ‒ amorphous state, ◊ ‒ crystalline state [6]; 1 ‒ assessment of the heat capacity of the NiZr2 intermetallic compound, 2 ‒ assessment of the heat capacity of the Ni2Zr compound) in the low-temperature region.

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3. Fig. 2. Temperature dependence of the linear thermal expansion coefficient of crystalline boron B (a; o ‒ values reduced by boron density [1]) and estimates (-----) of the behavior of the linear thermal expansion coefficients of Ni2B (b), Ni44Nb56 (1), Ni62Nb38 (2) and Ni0 alloys.333Zr0.667 [9] (d).

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