Modification of Nafion Membrane by Polycation in the Presemce of Lower Alyphatic Alcohols and Salt

Ju. A. Zakharova; Захарова Ю. А.; V. G. Sergeyev; Сергеев В. Г.

doi:10.31857/S2218117223030094

Modification of Nafion Membrane by Polycation in the Presemce of Lower Alyphatic Alcohols and Salt

Authors: Zakharova J.A.¹, Sergeyev V.G.¹
Affiliations:
1. Lomonosov Moscow State University, Chemical department
Issue: Vol 13, No 3 (2023)
Pages: 194-204
Section: Articles
URL: https://rjmseer.com/2218-1172/article/view/674341
DOI: https://doi.org/10.31857/S2218117223030094
EDN: https://elibrary.ru/ETRQJI
ID: 674341

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Abstract

Significant increase of ion selectivity was observed for Nafion membranes modified by poly(diallyldimethylammonium chloride), PDADMAC, in the presence of lower aliphatic alcohols and NaCl. It was found that addition of the salt into the alcohol-containing modification solutions resulted not only in decrease of diffusional permeability towards vanadyl ions, P, but also in simultaneous two- to threefold growth of proton conductivity, σ, in comparison with the membranes modified in the alcohol-water solutions in the absence of a salt. As a result, ion selectivity of the membranes calculated as σ/P ratio was increased in ∼4 orders of magnitude as compared with pristine Nafion 112 membrane. Conceivable mechanism of the ion selectivity increasing is proposed for the membranes modified by PDADMAC in the presence of lower aliphatic alcohols and NaCl.

Keywords

Nafion, membrane, isopropyl alcohol, PDADMAC, permeability, proton conductivity, ion selectivity, Bradford reagent

About the authors

Ju. A. Zakharova

Lomonosov Moscow State University, Chemical department

Author for correspondence.
Email: zakh@belozersky.msu.ru
Russia, 119899, Moscow

V. G. Sergeyev

Lomonosov Moscow State University, Chemical department

Author for correspondence.
Email: sergeyevvg@belozersky.msu.ru
Russia, 119899, Moscow

References

Alent’ev A.Yu., Volkov A.V., Vorotyntsev I.V., Maksimov A.L., Yaroslavtsev A.B. // Membranes and Membrane Technologies. 2021. V. 3. P. 255.
Wu J., Dai Q., Zhang H., Li X. // ChemSusChem. 2020.V. 13. P. 3805.
Machado C.A., Brown G.O., Yang R., Hopkins T.E., Pribyl J.G., Epps T.H. // ACS Energy Lett. 2021. V. 6. P. 158.
Mauritz K.A., Moore R.B. // Chem. Rev. // 2004. V. 104. P. 4535.
Gierke T.D., Munn G.E., Wilson F.C. // J Polym. Sci. Polym. Phys. 1981, V. 19. P. 1687.
Shi C., Liu T., Chen W., Cui F., Liu L., Cai Y., Li Y. // Polymer. 2021. V. 213. P. 123224.
Stenina I.A., Yaroslavtsev A.B. // Membranes 2021. V. 11. P. 198.
Апель П.Ю., Бобрешова О.В., Волков А. В., Волков В.В., Никоненко В.В., Стенина И.А., Филиппов А.Н., Ямпольский Ю.П., Ярославцев А.Б. // Мембраны и мембранные технологии, 2019. Т. 9. С. 59.
Yaroslavtsev A.B., Stenina I.A. // Mendeleev Commun. 2021. V. 31. P. 423.
Xiong P., Zhang L., Chen Y., Peng S., Yu G. // Angew. Chem. Int. Ed. 2021. V. 60. P. 2.
Thiam B.G., Vaudreuil S.J. // Electrochem Soc. 2021. V. 168. P. 070553.
Khoiruddin, Ariono D., Subagjo, Wenten I.G. // J. Appl. Polym. Sci. 2017. V. 134. P. 45540.
Amiri H., Khosravi M., Ejeian M., Razmjou A. // Adv. Mater. Technol. 2021. V. 6. P. 2001308.
Прихно И.А., Сафронова Е.Ю., Стенина И.А., Юрова П.А, Ярославцев А.Б. // Мембраны и мембранные технологии. 2020. Т. 10. С. 273.
Yang X.-B., Zhao L., Goh K., Sui X.-L., Meng L.-H., Wang Z.-B. // J. Energy Chem. 2020. V. 41. P. 177.
Hu L., Gao L., Yan X., Zheng W., Dai Y., Hao C., He G. // J. Mater. Chem. A. 2019. V. 7. P. 15 137.
Jeon C., Choi C., Kim H.-T., Seo M. // ACS Appl. Energy Mat. 2020. V. 3. P. 5874.
Xi J., Wu Z., Teng X., Zhao Y., Chen L., Qiu X. // J. Mater. Chem. 2008. V. 18. P. 1232.
Deligoz H., Yilmazturk S., Karaca T., Ozdemir H., Naci Koc S., Oksuzomer F., Durmus A., Gurkaynak M.A. // J. Membr. Sci. 2009. V. 326. P. 643.
Jiang S. P., Liu Z., Tian Z.Q. // Adv. Mater. 2006. V. 18. P. 1068.
Elliotta J.A., Hannaa S., Elliott A.M.S., Cooley G.E. // Polymer. 2001 V. 42. P. 2251.
Pyshkina O.A., Novoscoltseva O.A., Zakharova J.A. // Colloid Polym. Sci. 2019. V. 297. P. 423.
Zakharova J.A., Zansokhova M.F., Karpushkin E.A., Sergeyev V.G. // Mend. Commun. 2021. V. 31. P. 839.
Kasaikin V.A., Litmanovich E.A., Zezin A.B., Kaba-nov V.A. // Doklady Akademii Nauk SSSR. 1999. V. 367. P. 359.
Campbell R.A., Arteta M.Y., Angus-Smyth A., Nylander T., Varga I. // J. Phys. Chem. B. 2011. V. 115. P. 15202.
Pang F.-M., Seng C.-E., Teng T.-T., Ibrahim M.H. // J. Mol. Liq. 2007. V. 136. P. 71.
Zakharova J.A., Novoskoltseva O.A., Pyshkina O.A., Karpushkin E.A., Sergeyev V.G. // Coll. Polym. Sci. 2018. V. 296. P. 835.
Kondratenko M.S., Karpushkin E.A., Gvozdik N.A., Gallyamov M.O., Stevenson K.J., Sergeyev V.G. // J. Power Sources. 2017. V. 340. P. 32.
Bradford M.M. // Anal. Biochem. 1976. V. 72. P. 248.
Katzenberg A., Angulo A., Kusoglu A., Modestino M.A. // Macromolecules. 2021. V. 54. P. 5187.
Saito M., Tsuzuki S., Hayamizu K., Okada T. // J. Phys. Chem. B, V. 110. P. 24410.
Megriche A., Belhadj A., Mgaidi A. // Mediterr. J. Chem. 2012. V. 1. P. 200.
Rabinovich V.A., Chavin Z.Ya. // Short chemical guide, Leningrad, 1978 (in Russian).
Park J.-G., Lee S.-H., Hong Ju-K., Kim T.-G., Busnaina A.A. // J. Electrochem. Soc. 2006. V. 153. P. G811.
Randova A., Hovorka S., Izaґk P., Bartovska L. // J. Electroanal. Chem. 2008. V. 616. P. 117.
Pham T.D., Bui T.T., Nguen V.T., Bui T.K.V., Tran T.T., Pham Q.C., Hoang T.H. // Polymers. 2018. V. 10. P. 220.
Luo Q., Zhang H., Chen J., Qian P., Zhai Y. // J. Memb. Sci. 2008. V. 311. P. 98.
Claesson P. M., Poptoshev E., Blomberg E., Dedinaite A. // Adv. Coll. Interface Sci. 2005. V. 114–115. P. 173.
Shyichuk A., Ziolkowska D., Lamkiewich J. // Spectrosc. Spectr. Anal. 2016. V. 36. P. 583.
Compton S.J., Jones C.G. // Anal. Biochem. 1985. V. 151. P. 369.
Clark S.L., Montague M.F., Hammond P.T. // Macromolecules. 1997. V. 30. P. 7237.