Selective limiting concentration of the electrolyte solutions with singly and doubly charged cations

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The effect of the anion exchange layer of the copolymer N,N-diallyl-N,N-dimethylammonium chloride and methyl methacrylate on the electrochemical properties of a homogeneous perfluorosulfopolymer-based cation exchange membrane has been studied. Applying a modifying layer with a thickness of 5 microns to a membrane with a thickness of 215 microns leads to a decrease in electrical conductivity by no more than 35%, while the diffusion permeability decreases by more than 5 times and ceases to depend on concentration.

During membrane testing, similar levels of concentration were achieved in the process of the limiting electrodialysis concentration of sodium chloride solution. The effectiveness of a bilayer membrane for selective electrodialysis concentration was demonstrated. During the concentration of sodium and calcium chlorides mixture, the permselectivity coefficient P(Na+/Ca2+) ranged from 0.5 to 1.2 in the case of using the cation exchange membrane. Using a bilayer membrane led to a significant increase of the permselectivity coefficient, ranging from 1.5 to 2.7, depending on current density. This makes it possible to efficiently separate electrolytes with singly and doubly charged ions.

作者简介

N. Kovalchuk

Kuban State University; Platov South-Russian State Polytechnic University (NPI)

编辑信件的主要联系方式.
Email: kovol13@yandex.ru
俄罗斯联邦, Krasnodar; Novocherkassk

A. Minenko

Kuban State University

Email: kovol13@yandex.ru
俄罗斯联邦, Krasnodar

N. Romanyuk

Kuban State University

Email: kovol13@yandex.ru
俄罗斯联邦, Krasnodar

N. Smirnova

Platov South-Russian State Polytechnic University (NPI)

Email: kovol13@yandex.ru
俄罗斯联邦, Novocherkassk

S. Loza

Kuban State University

Email: kovol13@yandex.ru
俄罗斯联邦, Krasnodar

V. Zabolotsky

Kuban State University

Email: kovol13@yandex.ru
俄罗斯联邦, Krasnodar

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