Collapse of the inverse magnetocaloric effect in the ni47mn40sn13 alloy in cyclic magnetic fields

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Abstract

The results of direct measurements for the adiabatic temperature change ΔTad in the Ni47Mn40Sn13 alloy in cyclic magnetic fields by the magnetic field modulation method are presented. In the temperature dependence of the magnetocaloric effect (MCE), direct (ΔTad > 0) and inverse (ΔTad < 0) MCE are detected. The inverse effect value in a cyclic magnetic field depends on the temperature scanning rate. An increase in the frequency of a cyclic magnetic field with an induction of 1.2 T from 1 to 30 Hz decreases the direct effect value by more than 2 times. In a cyclic magnetic field with an induction of 1.2 T at frequencies f ≥1 Hz, complete disappearance (“collapse”) is observed for the inverse magnetocaloric effect, while ΔТad during the one-time actuation of magnetic field is –0.49 K. The dependence of the inverse effect value on the temperature scanning rate, along with its strong frequency dependence, results from both the manifestation of irreversibility in the magnetostructural phase transition due to hysteresis and the presence of phase inhomogeneities influencing the phase transition kinetics.

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A. G. Gamzatov

Amirkhanov Institute of Physics, DFRC

Author for correspondence.
Email: gamzatov_adler@mail.ru
Russian Federation, Makhachkala

A. B. Batdalov

Amirkhanov Institute of Physics, DFRC

Email: gamzatov_adler@mail.ru
Russian Federation, Makhachkala

A. M. Aliev

Amirkhanov Institute of Physics, DFRC

Email: gamzatov_adler@mail.ru
Russian Federation, Makhachkala

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2. Fig. 1. (a) Temperature dependence of magnetization of Ni47Mn40Sn13 in a magnetic field with induction of 20 mT (in the graph, replace FCC and FCH with cooling and heating); (b) temperature dependence of DTad in a cyclic magnetic field with induction of 1.8 T in heating and cooling modes at different rates of change of temperature of the sample. Solid circles are the values ​​of DTad for a single turn-on of a magnetic field of 1.8 T in the heating mode.

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3. Fig. 2. (a) Time dependence of DTad in a cyclic magnetic field with induction of 1.8 T (f=0.2 Hz) at T=213 K; (b) temperature dependence of DTad in a cyclic magnetic field with induction of 1.2 T at different frequencies of the cyclic magnetic field: 1, 5, 20 and 30 Hz. Open circles are the DTad values ​​for a single switch-on of a magnetic field of 1.2 T.

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4. Fig. 3. Dependence of the maximum of the direct and reverse effects on the magnetic field sweep speed.

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