The Evolution of the Magnetic Properties
of Iron Borate Single Crystals Doped with Gallium

N. I. Snegirev; Снегирёв Н. И.; A. V. Bogach; Богач А. В.; I. S. Lyubutin; Любутин И. С.; M. A. Chuev; Чуев М. А.; S. V. Yagupov; Ягупов С. В.; Yu. A. Mogilenec; Могиленец Ю. А.; K. A. Selezneva; Селезнева К. А.; M. B. Strugatsky; Стругацкий М. Б.

doi:10.31857/S0015323022601325

The Evolution of the Magnetic Properties of Iron Borate Single Crystals Doped with Gallium

作者: Snegirev N.I.¹, Bogach A.V.², Lyubutin I.S.¹, Chuev M.A.³, Yagupov S.V.⁴, Mogilenec Y.A.⁴, Selezneva K.A.⁴, Strugatsky M.B.⁴
隶属关系:
1. Shubnikov Institute of Crystallography, Federal Scientific Research Center Crystallography and Photonics, Russian Academy of Sciences
2. Prokhorov Institute of General Physics, Russian Academy of Sciences
3. Valiev Institute of Physics and Technology, Russian Academy of Sciences
4. Institute of Physics and Technology, V.I. Vernadsky Crimean Federal University
期: 卷 124, 编号 2 (2023)
页面: 141-145
栏目: ЭЛЕКТРИЧЕСКИЕ И МАГНИТНЫЕ СВОЙСТВА
URL: https://rjmseer.com/0015-3230/article/view/662756
DOI: https://doi.org/10.31857/S0015323022601325
EDN: https://elibrary.ru/KVXUCB
ID: 662756

如何引用文章

全文:

开放存取

##reader.subscriptionAccessGranted##
受限制的访问

订阅或者付费存取

详细

Highly perfect FeBO3 and Fe0.91Ga0.09BO3 single crystals were studied in a wide temperature range using SQUID magnetometry. A theoretical model describing the temperature and field dependences of the magnetization of single crystals has been developed. It is found that even a small concentration of gallium,
which is a diamagnetic impurity, substantially affects the magnetic properties of single FeBO3 crystals. In par-ticular, the Fe0.91Ga0.09BO3 crystal differs from the pure FeBO3 phase in by a lower magnetic phase transition temperature and a higher antiferromagnetic susceptibility at low temperatures.

关键词

iron borate, single crystals, magnetic properties, theoretical analysis

参考

Smirnova E.S., Snegirev N.I., Lyubutin I.S., Starchikov S.S., Artemov V.V., Lyubutina M.V., Yagupov S.V., Strugatsky M.B., Mogilenec Y.A., Seleznyova K.A., Alekseeva O.A. Flux growth, structure refinement and Mössbauer studies of Fe1 – xGaxBO3 single crystals. // Acta Crystallogr. B: Structural Science, Crystal Eng. Mater. 2020. V. 76(6) P. 1100–1108.
Yagupov S., Strugatsky M., Seleznyova K., Mogilenec Yu., Snegirev N., Marchenkov N., Kulikov A., Eliovich Ya., Frolov K., Ogarkova Yu., Lyubutin I. Development of a Synthesis Technique and Characterization of High-Quality Iron Borate FeBO3 Single Crystals for Applications in Synchrotron Technologies of a New Generation // Cryst. Growth Des. 2018. V. 18. P. 7435–7440.
Панкратов А.К., Стругацкий М.Б., Ягупов С.В. Газотранспортный синтез и морфология изометричных монокристаллов бората железа // Ученые записки ТНУ им. В.И. Вернадского. 2007. Т. 20(59). С. 64–73.
Joubert J.C., Shirk T., White W.B., Roy R. Stability, Infrared Spectrum and Magnetic Properties of FeBO3 // Mater. Res. Bull. 1968. V. 3. P. 671–676.
Pernet M., Elmale D., Joubert J. C. Structure Magnetique Du Metaborate de Fer FeBO3 // Solid State Commun. 1970. V. 8. P. 1583–1587.
Mogilenec Y., Seleznyova K., Yagupov S., Seleznev K., Nauhatsky I., Maksimova E., Strugatsky M. Structure of Fe1 – xMexBO3 (Me = Al, Sc) single crystals with low x‑values // J. Physics: Conference Series 2021. V. 2103. P. 012 069.
Mogilenec Y., Seleznyova K., Yagupov S., Strugatsky M., Kliava J. Dzyaloshinskii-Moriya interaction constant in iron-gallium borate single crystals // J. Phys.: Conference Series. 2020. V. 1697(1). P. 012083.
Seleznyova K., Strugatsky M., Yagupov S., Mogilenec Y., Drovosekov A., Kreine N., Rosa P., Kliava J. Electron magnetic resonance of iron-gallium borate single crystals // J. Appl. Physics. 2019. V. 125. P. 223905.
Yagupov S., Strugatsky M., Seleznyova K. Mogilenec Y., Milyukova E., Maksimova E., Nauhatsky I., Drovosekov A., Kreines N., Kliava J. Iron borate films: Synthesis and characterization // J. Magn. Magn. Mater. 2016. V. 417. P. 338–343.
Maksimova E.M., Nauhatsky I.A., Strugatsky M.B., Zubov V.E. Magnetism of real iron borate monocrystal // J. Magn. Magn. Mater. 2010. V. 322. P. 477–480.
Snegirev N.I., Lyubutin I.S., Yagupov S.V. Chuev M.A., Chumakov N.K., Zhigalina O.M., Khmelenin D.N., Strugatsky M.B. Size Effects in Iron Borate FeBO3 Nanoparticles // Russian J. Inorganic Chemistry. 2021. V. 66(8). P. 1217–1222.
Lyubutin I.S., Snegirev N.I., Chuev M.A., Starchikov S., Smirnova E., Lyubutina M., Yagupov S., Strugatsky M., Alekseeva O. Magnetic and electric hyperfine parameters of antiferromagnet FeBO3 intended for monochromatization of synchrotron radiation // J. Alloys and Compd. 2022. V. 906. P. 164348.
Snegirev N., Lyubutin I., Kulikov A., Zolotov D., Vasiliev A., Lyubutina M., Yagupov S., Mogilenec Y., Seleznyova K., Strugatsky M. Structural perfection of Fe1 – xGaxBO3 single crystals designed for nuclear resonant synchrotron experiments // J. Alloys and Compd. 2022. V. 889. P. 161 702.
Дорошев В.Д., Kовтун Н.М., Лукин С.Н., Молчанов А.Н. Базисная магнитная анизотропия слабого ферромагнетика FеВO3 // Письма в ЖЭТФ. 1979. Т. 29(5). С. 286–290.
Strugatsky M., Seleznyova K., Yagupov S., Drovosekov A., Kliava J. Nature of magnetocrystalline anisotropy in the basal plane of iron borate // J. Magn. Magn. Mater. 2017. V. 442. P. 417–422.
Вонсовский С.В. Магнетизм. М.: Наука. 1971. 1032 с.
Stoner E.C., Wohlfarth E.P. A mechanism of magnetic hysteresis in heterogeneous alloys // Phil. Trans. Royal Soc. London A. 1948. V. 240. P. 599–642.
Chuev M.A., Hesse J. Nanomagnetism: extension of the Stoner–Wohlfarth model within Néel’s ideas and useful plots // J. Phys.: Condens. Matter. 2007. V.19. P. 506 201.
Néel L. Influence des fluctuations thermiques sur l’aimantation de grains ferromagnétiques très fins // Comptes Rendus Hebdomadaires Des Seances De L Academie Des Sciences. 1949. V. 228(8). P. 664–666.
Yakimov S.S., Ozhogin V.I., Gamlitskii V.Ya. Cherepanov V.M., Pudkov S.D. Magnetic field induced antiferromagnetism in FeBO3 // Phys. Lett. A. 1972. V. 39A. N5. P. 421–423.
Великов Л.В., Рудашевский Е.Г., Селезнев В.Н. Наблюдение антиферромагнитного резонанса в борате железе выше температуры Нееля // Изв. АН СССР. Сер. физическая. 1972. № 7. С. 1531–1534.
Stanley H.E. Introduction to Phase Transitions and Critical Phenomena. Oxford University Press. 1971. P. 333.