Sorption of Metal Ions from Aqueous Solutions by Humic Substances

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Abstract

Humic substances (HSs) extracted from brown coal, peat, and other sources are considered as an
efficient and affordable sorbent used to trap and bind heavy metal ions, which are hazardous to the environment.
This paper provides an overview of modern works on this subject matter. Typical structural characteristics
and properties of HSs and methods for their extraction from brown coal, peat, swamp waters, and other
media are described, and quantitative results of a wide range of experiments on the sorption of metal ions by
HSs are presented. Significant fluctuations in the measured sorption capacity of HSs in different experiments
probably arise not so much due to variations in the elemental composition and structure of HSs extracted
from different sources, but they are associated with experimental conditions, such as the acidity (pH) of solution,
ionic strength, concentration of metal ions, and concentration of HSs in the solution. In terms of the
order of magnitude, the maximum sorption capacity of HSs is comparable to the total concentration of surface
carboxyl and hydroxyl groups, and it amounts to several millimoles of metal ions per gram of HSs

About the authors

Z. R. Ismagilov

Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Science

Email: zinfer1@mail.ru
Kemerovo, 650000 Russia

V. G. Smirnov

Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Science

Email: smirnovvg@mail.ru
Kemerovo, 650000 Russia

N. V. Malyshenko

Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Science

Email: profkemsc@yandex.ru
Kemerovo, 650000 Russia

S. I. Zherebtsov

Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Science

Author for correspondence.
Email: sizh@yandex.ru
Kemerovo, 650000 Russia

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