Influence of the Phase Composition of the Fe/Biochar Catalysts on the Composition of Fischer–Tropsch Synthesis Products: The Lapidus Theory of Bifunctional Catalytic Centers

M. I. Ivantsov; Иванцов М. И.; K. O. Krysanova; Крысанова К. О.; A. A. Grabchak; Грабчак А. А.; M. V. Kulikova; Куликова М. В.

doi:10.31857/S0023117723060026

Influence of the Phase Composition of the Fe/Biochar Catalysts on the Composition of Fischer–Tropsch Synthesis Products: The Lapidus Theory of Bifunctional Catalytic Centers

Authors: Ivantsov M.I.¹, Krysanova K.O.¹, Grabchak A.A.¹, Kulikova M.V.¹
Affiliations:
1. Topchiev Institute of Petrochemical Synthesis (TIPS), Russian Academy of Sciences
Issue: No 6 (2023)
Pages: 5-10
Section: Articles
URL: https://rjmseer.com/0023-1177/article/view/661682
DOI: https://doi.org/10.31857/S0023117723060026
EDN: https://elibrary.ru/BJLART
ID: 661682

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Abstract

Supported iron catalysts based on a carbon-containing material, biochar obtained by the hydrothermal carbonization of biopolymers (cellulose and lignin), were studied. The catalytic systems showed high activity in the Fischer–Tropsch synthesis. A composition of C5+ liquid products, uncharacteristic for ironcontaining catalysts, characterized by high isoalkane content (up to 55%) was recorded. This fact was discussed in the context of the theory of bifunctional centers proposed by A.L. Lapidus with coworkers. It was suggested that the active centers of the test catalysts can be considered bifunctional (a carbide phase and an oxide phase). A correlation between the Fischer–Tropsch synthesis data on the test catalysts and the data obtained by Lapidus and coworkers on cobalt-containing catalysts was shown.

Keywords

Fischer–Tropsch synthesis, Fe/biochar, hydrothermal carbonization, lignin, cellulose

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