Preparation of highly effective carbon adsorbents based on high-moor peat from the European North of Russia

封面

如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅存取

详细

The study of active coals obtained from high-moor peat of the European North of Russia was conducted by method of thermochemical activation with NaOH with various types of pre-treatment (debituminization and pre-hydrolysis). Based on the results of the low-temperature adsorption of nitrogen, the derived active coals belong to the adsorbents in which the structure of the micro-agents predominates. The specific surface of the coal pores reaches 2330 m2/g, the total volume of pores – 1.44 cm3/g. It has been determined that the introduction of the pre-hydrolysis stage makes it possible to increase significantly the yield of active coals. For initial peat samples, the growth is 28%; for debituminized – 97%, moreover it significantly improve its sorption characteristics. It has been shown that weakly decomposed peat of the European North of Russia can be used as raw material for producing high-efficiency carbon microporous adsorbents.

全文:

受限制的访问

作者简介

I. Zubov

Laverov Federal Center for Integrated Arctic Research of the Ural Branch of the Russian Academy of Sciences

编辑信件的主要联系方式.
Email: zubov.ivan@fciarctic.ru
俄罗斯联邦, Arkhangelsk, 163002

Y. Savrasova

Northern (Arctic) Lomonosov Federal University

Email: yulia925@mail.ru
俄罗斯联邦, Arkhangelsk, 163002

N. Bogdanovich

Northern (Arctic) Lomonosov Federal University

Email: n.bogdanovich@narfu.ru
俄罗斯联邦, Arkhangelsk, 163002

参考

  1. Trevino-Cordero H., Juarez-Aguilar L.G., Mendoza-Castillo D.I. et al. // Ind. Crops Prod. 2013. V. 42. P. 315–323. https://doi.org/10.1016/j.indcr op.2012.05.029
  2. Bergna D., Hu T., Prokkola H., Romar H., Lassi U. // Waste and Biomass Valorization. 2020. V. 11. P. 2837–2848. https://doi.org/10.1007/s12649-019-00584-2
  3. Мухин В.М., Клушин В.Н. Производство и применение углеродных адсорбентов. М.: РХТУ им. Д.И. Менделеева. 2012. 308 с.
  4. Lahti R., Bergna D., Romar H., Hu T. et al. // Top. Catal. 2017. V. 60. № 17–18. P. 1415–1428.https://doi.org/10.1007/s11244-017-0823-z
  5. Lee J., Kim K.H., Kwon E.E. // Renew Sust. Energy Rev. 2017. V. 77. P. 70–79.
  6. Harmas M.,· Palm R.,· Thomberg T.· et al. // Journal of Applied Electrochemistry. 2020. V. 50. P. 15–32.https://doi.org/10.1007/s10800-019-01364-5
  7. Zuo W., Li R., Zhou C. et al. // Adv. Sci. 2017. V. 4. № 7. Art. 1600359.https://doi.org/10.1002/advs.201600539
  8. Мухин В.М., Тарасов А.В., Клушин В.Н. Активные угли России / Под общ. ред. Тарасова А.В. М.: Металлургия, 2000. 352 с.
  9. Активные угли. Эластичные сорбенты. Катализаторы, осушители и химические поглотители на их основе: каталог / Под общ. ред. Мухина В.М. М.: Руда и металлы, 2003. 280 с.
  10. Суровикин Ю.В., Лихолобов В.А., Сергеев В.В., Макаров И.В. // ХТТ. 2014. № 6. С. 47–56 [Solid Fuel Chemistry, 2014, vol. 48, № 6, pp. 371–381.https://doi.org/10.3103/S0361521914060081].
  11. Калиничева О.А., Богданович Н.И., Добеле Г.В. // Известия вузов. Лесной журнал. 2008. № 2. С. 117–122.
  12. Lishtvan I.I., Selyanina S.B., Trufanova M.V. et al. // Solid Fuel Chemistry. 2021. V. 55. № 4. P. 244–251.https://doi.org/10.31857/S0023117721040034
  13. Zubov I.N., Orlov A.S., Popovb A.N., Ponomareva T. I., Losyuk G.N. // Solid Fuel Chemistry. 2022. V. 56. № 5. P. 330–335.https://doi.org/10.3103/s0361521922050123
  14. Селянина С.Б., Татаринцева В.Г., Серебренникова О.В., Орлов А.С. // Успехи современного естествознания. 2019. № 5. С. 83–88.
  15. ASTM D 2866 – 11. Standard Test Method for Total Ash Content of Activated Carbon. – Intr. 1983. – PA, USA.: ASTM Intern., 2011. – 35 p.
  16. Орлов А.С., Зубов И.Н., Яковлев Е.Ю., Богданович Н.И. // ХТТ. 2023. № 5. С. 50–54.https://doi.org/10.31857/S0023117723050055[Solid Fuel Chemistry, 2023, vol. 57, № 5, pp. 343–347.https://doi.org/10.3103/S0361521923050051].
  17. Макаревич Н.А. Межфазная граница “газ–жидкость–твердое тело”: монография / Сев. (Арктич.) фед. ун-т им. М.В. Ломоносова. Архангельск САФУ. 2018. 411 c.

补充文件

附件文件
动作
1. JATS XML
2. Fig. 1. Scheme of coal washing from co-products.

下载 (118KB)
3. Fig. 2. Nitrogen adsorption–desorption isotherms.

下载 (65KB)
4. Fig. 3. Diagram of the pore size distribution.

下载 (62KB)

版权所有 © Russian Academy of Sciences, 2024