Study of electrical properties and characterization of a metal-polymer conductor based on silver-containing nanowires

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Abstract

The possibility of forming a conductive metal-polymer composite based on an array of intersecting silver-containing nanowires has been demonstrated. It has been determined that the electrical and mechanical characteristics of the composites depend both on the deposition time and on the ratio of the anode to cathode areas. The resulting metal-polymer composites had mechanical characteristics exceeding those of polymer track membranes made of polyethylene terephthalate. At the same time, with an increase in the ratio of anode to cathode areas and an increase in deposition time, the samples exhibit a decrease in the values of electrical conductivity (0.0025 Ω-1 – at 100 growth cycles, 0.0033 Ω-1 – at 50 cycles), strength (90 MPa – at 100 cycles, 99 MPa – at 50 cycles) and elastic modulus (4.7 GPa – at 100 cycles, 5.4 GPa – at 50 cycles). The data obtained indicate that conductive silver-containing nanowires can be reinforcing structures for conductive metal-polymer composites with high electrical conductivity values, promising for use in flexible electronics elements.

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About the authors

D. V. Panov

NRC “Kurchatov Institute”

Author for correspondence.
Email: dggamer@mail.ru

Shubnikov Institute of Crystallography of Kurchatov Complex of Crystallography and Photonics

Russian Federation, Moscow

I. S. Volchkov

NRC “Kurchatov Institute”

Email: dggamer@mail.ru

Shubnikov Institute of Crystallography of Kurchatov Complex of Crystallography and Photonics

Russian Federation, Moscow

N. P. Kovalets

Moscow Pedagogical State University

Email: dggamer@mail.ru
Russian Federation, Moscow

P. L. Podkur

NRC “Kurchatov Institute”

Email: dggamer@mail.ru

Shubnikov Institute of Crystallography of Kurchatov Complex of Crystallography and Photonics

Russian Federation, Moscow

I. O. Koshelev

NRC “Kurchatov Institute”

Email: dggamer@mail.ru

Shubnikov Institute of Crystallography of Kurchatov Complex of Crystallography and Photonics

Russian Federation, Moscow

V. M. Kanevskiy

NRC “Kurchatov Institute”

Email: dggamer@mail.ru

Shubnikov Institute of Crystallography of Kurchatov Complex of Crystallography and Photonics

Russian Federation, Moscow

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Supplementary files

Supplementary Files
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2. Fig. 1. SEM image of a 100 nm diameter silver nanowire mesh after removal of the polymer track membrane.

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3. Fig. 2. Diagram of the anode location relative to the sample cutting zones.

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4. Fig. 3. SEM image of a composite sample from the cross-sectional side (1) and the matrix plane (2).

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5. Fig. 4. Diffraction patterns of samples of the first (a) and second (b) series.

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6. Fig. 5. Dependences for the first (squares) and second (circles) composite samples on the ratio of the anode area to the cathode area O: a – tensile strength P, b – elastic modulus E, c – inverse resistance 1/R.

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7. Fig. 6. SEM image of the first (a) and second (b) composite samples. Arrows indicate the lengths of the nanowires.

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