DETERMINATION OF THE ABSOLUTE CONFIGURATION OF MONOATOMIC CHIRAL CRYSTALS USING THREE-WAVE X-RAY DIFFRACTION

K. A. Kozlovskaya; Козловская К. А.; E. N. Ovchinnikova; Овчинникова Е. Н.; A. M. Ustyugov; Устюгов А. М.; V. E. Dmitrienko; Дмитриенко В. Е.; A. P. Oreshko; Орешко А. П.

doi:10.31857/S0023476123700066

DETERMINATION OF THE ABSOLUTE CONFIGURATION OF MONOATOMIC CHIRAL CRYSTALS USING THREE-WAVE X-RAY DIFFRACTION

Authors: Kozlovskaya K.A.¹, Ovchinnikova E.N.¹, Ustyugov A.M.¹, Dmitrienko V.E.², Oreshko A.P.¹
Affiliations:
1. Lomonosov Moscow State University, Moscow, 119991 Russia
2. Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,” Russian Academy of Sciences, Moscow, 119333 Russia
Issue: Vol 68, No 3 (2023)
Pages: 370-375
Section: ДИФРАКЦИЯ И РАССЕЯНИЕ ИОНИЗИРУЮЩИХ ИЗЛУЧЕНИЙ
URL: https://rjmseer.com/0023-4761/article/view/673436
DOI: https://doi.org/10.31857/S0023476123700066
EDN: https://elibrary.ru/WZXZDW
ID: 673436

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Abstract

Many molecules and crystals are chiral, i.e., can exist as right- and left-handed mirror isomers. It is shown that the absolute configuration of monoatomic chiral crystals, including selenium, tellurium, and b-manganese, can be determined using multi-wavelength diffraction of circularly polarized X-ray radiation.

Keywords

ABSOLUTE CONFIGURATION, CHIRAL CRYSTALS, THREE-WAVE X-RAY DIFFRACTION

About the authors

K. A. Kozlovskaya

Lomonosov Moscow State University, Moscow, 119991 Russia

Email: kozlovskaya@physics.msu.ru
Россия, Москва

E. N. Ovchinnikova

Lomonosov Moscow State University, Moscow, 119991 Russia

Email: ovtchin@gmail.com
Россия, Москва

A. M. Ustyugov

Lomonosov Moscow State University, Moscow, 119991 Russia

Email: kozlovskaya@physics.msu.ru
Россия, Москва

V. E. Dmitrienko

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,” Russian Academy of Sciences, Moscow, 119333 Russia

Email: ovtchin@gmail.com
Россия, Москва

A. P. Oreshko

Lomonosov Moscow State University, Moscow, 119991 Russia

Author for correspondence.
Email: ap.oreshko@physics.msu.ru
Россия, Москва

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