FILLING OF CHANNELS OF THE ZEOLITE FRAMEWORK IN TRIGONAL POLAR NONABORATE Ва3Na0.9(OH)1.9[B9O16][B(OH)3]

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Abstract

Crystals of the new trigonal borate Ва3Na0.9(OH)1.9[B9O16][B(OH)3] (sp. gr. P31c, a =10.23684(15) Å, c = 8.72926(13) Å) were prepared by the mild hydrothermal synthesis. The filling of the channels in the framework of the polar nonaborate was found to differ from that determined previously. It is consistent with the main features of this structure type with the preservation of sassoline molecules in the channels. The structure contains an additional ОН group, which is involved in the coordination of Ва.

About the authors

A. P. Topnikova

Lomonosov Moscow State University, Moscow, 119991 Russia

Email: nastya_zorina@rambler.ru
Россия, Москва

E. L. Belokoneva

Lomonosov Moscow State University, Moscow, 119991 Russia

Email: nastya_zorina@rambler.ru
Россия, Москва

O. V. Dimitrova

Lomonosov Moscow State University, Moscow, 119991 Russia

Email: nastya_zorina@rambler.ru
Россия, Москва

A. S. Volkov

Lomonosov Moscow State University, Moscow, 119991 Russia

Email: nastya_zorina@rambler.ru
Россия, Москва

L. V. Zorina

Osipyan Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, Moscow region, 142432 Russia

Author for correspondence.
Email: nastya_zorina@rambler.ru
Россия, Черноголовка

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