FILLING OF CHANNELS OF THE ZEOLITE FRAMEWORK IN TRIGONAL POLAR NONABORATE Ва 3 Na 0.9 (OH) 1.9 [B 9 O 16 ][B(OH) 3 ]

A. P. Topnikova; Топникова А. П.; E. L. Belokoneva; Белоконева Е. Л.; O. V. Dimitrova; Димитрова О. В.; A. S. Volkov; Волков А. С.; L. V. Zorina; Зорина Л. В.

doi:10.31857/S0023476123020200

FILLING OF CHANNELS OF THE ZEOLITE FRAMEWORK IN TRIGONAL POLAR NONABORATE Ва₃Na_0.9(OH)_1.9[B₉O₁₆][B(OH)₃]

Authors: Topnikova A.P.¹, Belokoneva E.L.¹, Dimitrova O.V.¹, Volkov A.S.¹, Zorina L.V.²
Affiliations:
1. Lomonosov Moscow State University, Moscow, 119991 Russia
2. Osipyan Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, Moscow region, 142432 Russia
Issue: Vol 68, No 2 (2023)
Pages: 223-227
Section: СТРУКТУРА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://rjmseer.com/0023-4761/article/view/673493
DOI: https://doi.org/10.31857/S0023476123020200
EDN: https://elibrary.ru/BSWCKC
ID: 673493

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

Crystals of the new trigonal borate Ва₃Na_0.9(OH)_1.9[B₉O₁₆][B(OH)₃] (sp. gr. P31c, a =10.23684(15) Å, c = 8.72926(13) Å) were prepared by the mild hydrothermal synthesis. The filling of the channels in the framework of the polar nonaborate was found to differ from that determined previously. It is consistent with the main features of this structure type with the preservation of sassoline molecules in the channels. The structure contains an additional ОН group, which is involved in the coordination of Ва.

Keywords

HYDROTHERMAL SYNTHESIS, TRIGONAL POLAR NONABORATE

References

The Cambridge Crystallographic Data Centre (CCDC). Inorganic Crystal Structure Data Base – ICSD. https://www.ccdc.cam.ac.uk/, http://www.fiz-karlsruhe.de
Crystallography Open Database. crystallography.net/cod
Christ C.L., Clark J.R. // Phys. Chem. Miner. 1977. V. 2. P. 59.
Liu L., Su X., Yang Y. et al. // Dalton Trans. 2014. V. 43. P. 8905.
Smith R.W., Keszler D.A. // Mater. Res. Bull. 1989. V. 24. P. 725.
Bubnova R.S., Krivovichev S.V., Filatov S.K. et al. // J. Solid State Chem. 2007. V. 180. P. 596.
Белоконева Е.Л., Стефанович С.Ю., Димитрова О.В. // Кристаллография. 2012. Т. 57. С. 70.
Wei Q., Sun L., Zhang J., Yang G.-Y. // Dalton Trans. 2017. V. 46. P. 7911.
Heyward C., McMillen C.D., Kolis J. // J. Solid State Chem. 2013. V. 203. P. 166.
Chen X., Wu L., Chang X., Xiao W. // Solid State Sci. 2014. V. 27. P. 47.
Топникова А.П., Белоконева Е.Л. // Успехи химии. 2019. Т. 88. № 2. С. 204.
Белоконева Е.Л., Стефанович С.Ю., Димитрова О.В. и др. // Кристаллография. 2009. Т. 54. № 5. С. 860.
Agilent (2014). CrysAlis PRO. Agilent Technologies Ltd, Yarnton, Oxfordshire, England.
Sheldrick G.M. // Acta Cryst. A. 2008. V. 64. P. 112.
Farrugia L.J. // J. Appl. Cryst. 2012. V. 45. P. 849.
Белоконева Е.Л., Стефанович С.Ю., Борисова Т.А., Димитрова О.В. // Журн. неорган. химии. 2001. Т. 46. С. 1788.
Sheldrick G.M. // Acta Cryst. C. 2015. V. 71. P. 3.
Dowty E. ATOMS. Shape Software, Kingsport, Tennessee, USA, 2006.
Grube H.H. // Fortsch. Mineral. 1981. B. 59. S. 58.
Lu J., Shi G., Wu H. et al. // RSC Adv. 2017. V. 7. P. 20259.
Wu Ch., Song J., Li L. et al. // J. Mater. Chem. C. 2016. V. 4. P. 8189.
Wei Q., Wang J.-J., He Ch. et al. // Chem. Eur. J. Commun. 2016. V. 22. P. 10759.
Wu Ch., Jiang X., Lin L. et al. // Angew. Chem. Int. Ed. 2021. V. 60. № 52. P. 27151.