Ring Silicates Cs4Tm2[Si4O12](OH)2 and Cs4(Tm,Tb)2[Si4O12](OH)2 As Merohedral Twins

N. B. Bolotina; Болотина Н. Б.; A. P. Topnikova; Топникова А. П.; E. L. Belokoneva; Белоконева Е. Л.; O. V. Dimitrova; Димитрова О. В.; A. S. Volkov; Волков А. С.; L. V. Zorina; Зорина Л. В.

doi:10.31857/S0023476123010058

Ring Silicates Cs4Tm2[Si4O12](OH)2 and Cs4(Tm,Tb)2[Si4O12](OH)2 As Merohedral Twins

Authors: Bolotina N.B.¹, Topnikova A.P.², Belokoneva E.L.², Dimitrova O.V.², Volkov A.S.², Zorina L.V.³
Affiliations:
1. Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,” Russian Academy of Sciences, 119333, Moscow, Russia
2. Moscow State University, 119991, Moscow, Russia
3. Institute of Solid State Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia
Issue: Vol 68, No 1 (2023)
Pages: 18-24
Section: СТРУКТУРА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://rjmseer.com/0023-4761/article/view/673530
DOI: https://doi.org/10.31857/S0023476123010058
EDN: https://elibrary.ru/DNOCPX
ID: 673530

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Abstract

New ring silicates Cs4Tm2[Si4O12](OH)2 and Cs4(Tm,Tb)2[Si4O12](OH)2 have been synthesized by the hydrothermal method. A structural analogy is revealed between them and the previously studied silicates K4Sc2(OH)2(Si4O12) and K2Sc[Si2O6]F. Their crystal structures are identified as orthorhombic merohedral twins by the lost element of tetragonal symmetry. The structures of new ring silicates are related to those of fresnoite and tetragonal melilite.

Keywords

RING SILICATES, HYDROTHERMAL METHOD, CRYSTAL STRUCTURE

About the authors

N. B. Bolotina

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,” Russian Academy of Sciences, 119333, Moscow, Russia

Email: bolotina@crys.ras.ru
Россия, Москва

A. P. Topnikova

Moscow State University, 119991, Moscow, Russia

Email: bolotina@crys.ras.ru
Россия, Москва

E. L. Belokoneva

Moscow State University, 119991, Moscow, Russia

Email: bolotina@crys.ras.ru
Россия, Москва

O. V. Dimitrova

Moscow State University, 119991, Moscow, Russia

Email: bolotina@crys.ras.ru
Россия, Москва

A. S. Volkov

Moscow State University, 119991, Moscow, Russia

Email: bolotina@crys.ras.ru
Россия, Москва

L. V. Zorina

Institute of Solid State Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

Author for correspondence.
Email: bolotina@crys.ras.ru
Россия, Черноголовка

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