Synthesis, crystal structure and spectroscopic study of lead monochloroacetate, Pb(ClCH2COO)2

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Abstract

Crystals of lead monochloroacetate, Pb(ClCH2COO)2, were obtained in the reaction of lead carbonate and aqueous chloroacetic acid. The compound crystallizes in the monoclinic symmetry (space group P21/c) with the unit cell parameters: a = 10.8346(6), b = 7.7239(4), c = 10.1484(5) Å, β = 106.542(5)°. Like other medium- and long-chain lead carboxylates, the crystal structure of lead monochloroacetate is layered. Lead atoms are located in distorted seven-vertex PbO7-polyhedra which share edges and form layers. Features of the crystal structures of lead salts of carboxylic acids with unbranched hydrocarbon radicals are discussed. In particular, salts of lead(II) n-alkyl carboxylates with the general formula Pb(CnH2n+1COO)2, despite belonging to different symmetry and space groups (monoclinic P21/m for n = 2 and 3, triclinic P1 for n = 4–9, and monoclinic P21/c for Pb(ClCH2COO)2), are characterized by the same arrangement of molecules, so they can be considered structurally related.

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About the authors

S. A. Ivanov

Lomonosov Moscow State University; FRC Kola Science Centre RAS

Email: aks.crys@gmail.com

Faculty of Chemistry, Lomonosov Moscow State University; Laboratory of Arctic Mineralogy and Material Sciences, FRC Kola Science Centre RAS

Russian Federation, 1-3 Leninskie Gory, Moscow 119991; 14 Fersman str., Apatity 184209

A. M. Banaru

Lomonosov Moscow State University; FRC Kola Science Centre RAS

Email: aks.crys@gmail.com

Faculty of Chemistry, Lomonosov Moscow State University; Laboratory of Arctic Mineralogy and Material Sciences, FRC Kola Science Centre RAS

Russian Federation, 1-3 Leninskie Gory, Moscow 119991; 14 Fersman str., Apatity 184209

V. E. Kireev

FRC Kola Science Centre RAS

Email: aks.crys@gmail.com

Laboratory of Arctic Mineralogy and Material Sciences

Russian Federation, 14 Fersman str., Apatity 184209

D. O. Charkin

Lomonosov Moscow State University; FRC Kola Science Centre RAS

Email: aks.crys@gmail.com

Faculty of Chemistry, Lomonosov Moscow State University; Laboratory of Arctic Mineralogy and Material Sciences, FRC Kola Science Centre RAS

Russian Federation, 1-3 Leninskie Gory, Moscow 119991; 14 Fersman str., Apatity 184209

A. A. Kompanchenko

FRC Kola Science Centre RAS

Email: aks.crys@gmail.com

Geological Institute

Russian Federation, 14 Fersman str., Apatity 184209

A. N. Gosteva

FRC Kola Science Centre RAS; Federal State Autonomous Educational Institution of Higher Education “Murmansk Arctic University”

Email: aks.crys@gmail.com

I.V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, FRC Kola Science Centre RAS

Russian Federation, 26a, Akademgorodok, Apatity 184209; 15 Kapitana Egorova str., Murmansk 183038

S. M. Aksenov

FRC Kola Science Centre RAS

Author for correspondence.
Email: aks.crys@gmail.com

Laboratory of Arctic Mineralogy and Material Sciences; Geological Institute

Russian Federation, 14 Fersman str., Apatity 184209

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Supplementary files

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2. Fig. 1. Raman spectrum of lead monochloroacetate Pb(ClCH2COO)2. Regions (a) and (b) are highlighted in the overall spectrum (c).

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3. Fig. 2. IR spectrum of lead monochloroacetate Pb(ClCH2COO)2.

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4. Fig. 3. General view of the crystal structure of the compound Pb(ClCH2COO)2 (a) and structural features of the electrically neutral layer {Pb(ClCH2COO)2} (b).

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5. Fig. 4. Coordination environment of the Pb2+ cation in the crystal structure of Pb(ClCH2COO)2.

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6. Fig. 5. Networks kgd (a) and sdf (b) in RCSR [27].

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7. Fig. 6. The 3,4,7L7 network in its most symmetrical implementation on a plane. Black circles correspond to relaxed cation positions, gray circles to anion positions.

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