LOCAL ATOMIC ENVIRONMENT OF Zn 2+  IONS IN A LOW-CONCENTRATION ZnCl 2  AQUEOUS SOLUTION: XANES STUDY

V. Yu. Lysenko; Лысенко В. Ю.; M. A. Kremennaya; Кременная М. А.; G. E. Yalovega; Яловега Г. Э.

doi:10.31857/S002347612302011X

LOCAL ATOMIC ENVIRONMENT OF Zn²⁺ IONS IN A LOW-CONCENTRATION ZnCl₂ AQUEOUS SOLUTION: XANES STUDY

Авторлар: Lysenko V.Y.¹, Kremennaya M.A.¹, Yalovega G.E.¹
Мекемелер:
1. Faculty of Physics, Southern Federal University, Rostov-on-Don, 344090 Russia
Шығарылым: Том 68, № 2 (2023)
Беттер: 228-233
Бөлім: СТРУКТУРА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://rjmseer.com/0023-4761/article/view/673494
DOI: https://doi.org/10.31857/S002347612302011X
EDN: https://elibrary.ru/BQHCUB
ID: 673494

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат
Рұқсат жабық

Рұқсат берілді
Рұқсат жабық

Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

The diverse local environment of zinc ions in a ZnCl₂ solution, depending on the symmetry, ligand type, and solution concentration, has been analyzed using the data in the literature. Experimental zinc K-edge XANES spectra in a ZnCl₂ aqueous solution with a critically low concentration (10^–3 М) have been theoretically analyzed. It is shown that Zn(H₂O) complexes with Zn²⁺ ions in the octahedral coordination environment of water molecules are dominant in this solution.

Негізгі сөздер

ZnCl2 AQUEOUS SOLUTION, XANES STUDY

Авторлар туралы

V. Lysenko

Faculty of Physics, Southern Federal University, Rostov-on-Don, 344090 Russia

Email: yalovega@sfedu.ru
Россия, Ростов-на-Дону

M. Kremennaya

Faculty of Physics, Southern Federal University, Rostov-on-Don, 344090 Russia

Email: yalovega@sfedu.ru
Россия, Ростов-на-Дону

G. Yalovega

Faculty of Physics, Southern Federal University, Rostov-on-Don, 344090 Russia

Хат алмасуға жауапты Автор.
Email: yalovega@sfedu.ru
Россия, Ростов-на-Дону

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