Photo-fenton reaction for the decomposition of RR195 dye in the presence of the metal-organic polymer MIL-53(Fe3+) and a composite with graphene oxide

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The metal-organic polymer of the composition Fe(OH)(BDC)×(H2O)2 – MIL-53(Fe) and the composite MIL-53(Fe)/GO (GO – graphene oxide) were obtained by the solvothermal method and characterized by X-ray diffraction and X-ray absorption and IR-Fourier spectroscopy, scanning electron microscopy. The presence of Fe2+ and Fe3+ ions in MIL-53(Fe) and MIL-53(Fe)/GO was established with a higher content of Fe2+ ions in MIL-53(Fe)/GO, which helps to increase the efficiency of the decomposition reaction of the RR195 dye, which is actively used in textile industry for dyeing fabrics in the photo-Fenton reaction.

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作者简介

G. Kuz’micheva

MIREA – Russian Technological University

Email: ms.asenka1984@mail.ru
俄罗斯联邦, 78 Vernadsky Avenue, Moscow, 119454

A. Gainanova

MIREA – Russian Technological University

编辑信件的主要联系方式.
Email: ms.asenka1984@mail.ru
俄罗斯联邦, 78 Vernadsky Avenue, Moscow, 119454

Ke Nguyen

MIREA – Russian Technological University

Email: ms.asenka1984@mail.ru
俄罗斯联邦, 78 Vernadsky Avenue, Moscow, 119454

E. Khramov

National Research Center “Kurchatov Institute”

Email: ms.asenka1984@mail.ru
俄罗斯联邦, 1 Akademika Kurchatova pl., Moscow 123182

R. Svetogorov

National Research Center “Kurchatov Institute”

Email: ms.asenka1984@mail.ru
俄罗斯联邦, 1 Akademika Kurchatova pl., Moscow 123182

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2. Fig. 1. Scheme of synthesis of MIL-53(Fe)/GO and MIL-53(Fe) samples.

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3. Fig. 2. Diffraction patterns of experimental samples MIL-53(Fe)/GO (1), MIL-53(Fe)-I (2), MIL-53(Fe)-II (3) and theoretical bar chart of sample MIL-53(Fe) (recalculated to CuKα) from CCDC database #690316 (a). Solid arrows indicate reflections of impurity phase/phases, dashed arrows indicate reflections of graphene oxide. Diffraction pattern of graphene oxide (b). Schematic representation of change in shape of fragment of MIL-53(Fe)/GO framework (c).

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4. Fig. 3. XANES (a) and EXAFS spectra (b) at the K-edge of Fe absorption of samples MIL-53(Fe)/GO (1), MIL-53(Fe)-I (2), MIL-53(Fe)-II) (3) and standards FeO (4), α-Fe2O3 (5), γ-Fe2O3 (6), Fe (7).

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5. Fig. 4. FTIR spectra of MIL-53(Fe)-II (1) and MIL-53(Fe)/GO (2) samples.

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6. Fig. 5. SEM (a, b) and TEM images (c, d) of MIL-53(Fe)-II (a, c) and MIL-53(Fe)/GO (b, d) samples (arrows indicate MIL-53(Fe) nanoparticles); SEM image of the MIL-53(Fe)/GO composite with iron mapping (d).

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7. Fig. 6. Kinetic curves of photodegradation of RR195 dye: a – in the presence of H2O2 (1), MIL-53(Fe)/GO (2, 4) and MIL-53(Fe)-II (3) photocatalysts upon introduction of 0.4 ml of H2O2 (3, 4) into the photoreaction mixture and irradiation with visible light (1, 3, 4); b – at a volume of H2O2 introduced into the mixture of 0.2 (1), 0.4 (2), 0.6 ml (3); c – mixture pH 3 (1), 5.5 (2), 7.5 (3); d – initial concentration of RR195 150 (1), 125 (2), 100 ppm (3); d – stability of catalytic activity in the first (1), second (2) and third (3) photoreaction cycles.

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