Separation of Industrial Mixture of Decalin or Naphthalene Fluorination Products. Physical-Chemical Foundations of Crystallizing Binary Mixtures of cis- and trans-Perfluorodecalin and Perfluorobutylcyclohexane

A. V. Polkovnichenko; Полковниченко А. В.; N. N. Kulov; Кулов Н. Н.; A. V. Kisel’; Кисель А. В.; N. N. Kuritsyn; Курицын Н. Н.; S. Ya. Kvashnin; Квашнин С. Я.; E. V. Lunachev; Лупачев Е. В.

doi:10.31857/S0040357123060179

Separation of Industrial Mixture of Decalin or Naphthalene Fluorination Products. Physical-Chemical Foundations of Crystallizing Binary Mixtures of cis- and trans-Perfluorodecalin and Perfluorobutylcyclohexane

Authors: Polkovnichenko A.V.¹, Kulov N.N.¹, Kisel’ A.V.¹, Kuritsyn N.N.¹, Kvashnin S.Y.¹, Lunachev E.V.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry RAS
Issue: Vol 57, No 6 (2023)
Pages: 638-645
Section: Articles
Published: 01.11.2023
URL: https://rjmseer.com/0040-3571/article/view/652839
DOI: https://doi.org/10.31857/S0040357123060179
EDN: https://elibrary.ru/IGHVCO
ID: 652839

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Abstract

Physical–chemical data on the liquid–solid phase transitions in the binary systems trans-PFD–cis-PFD, trans-PFD–BCH, and cis-PFD–BCH are obtained. All three systems are characterized by the presence of a temperature extremum on the fusibility curve. For the trans-PFD–BCH system, the liquidus line can be described by the equation for simple eutectic systems with the assumed activity coefficient = 1, which indicates that the behavior of the system is close to ideal. The process of bulk crystallization is considered using the example of a cis-PFD–BCH mixture. It is demonstrated that from cis-PFD–BCH mixtures
with an initial content xcis-PFD = 0.7348 and 0.6447 mol. fr., cis-PFD can be isolated with a purity of more than 0.99 mol. fr. in three crystallization cycles.

Keywords

perfluorocycloalkanes, perfluorobutylcyclohexane, perfluorodecalin, separation of isomers, crystallization, fusibility curve, liquid–solid phase equilibrium

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