Correction of the 3D Computer Model of the Phase Diagram for the LiCl–PrCl3–KCl System Using Thermoanalytical Curves

V. P. Vorob’eva; Воробьева В. П.; A. E. Zelenaya; Зеленая А. Э.; V. I. Lutsyk; Луцык В. И.; M. D. Parfenova; Парфенова М. Д.; V. D. Baldanov; Балданов В. Д.

doi:10.31857/S0044457X23600524

Correction of the 3D Computer Model of the Phase Diagram for the LiCl–PrCl3–KCl System Using Thermoanalytical Curves

Authors: Vorob’eva V.P.¹, Zelenaya A.E.¹, Lutsyk V.I.¹, Parfenova M.D.¹, Baldanov V.D.¹
Affiliations:
1. Institute of Physical Materials Science, Siberian Branch of the Russian Academy of Sciences
Issue: Vol 68, No 8 (2023)
Pages: 1090-1098
Section: ФИЗИКО-ХИМИЧЕСКИЙ АНАЛИЗ НЕОРГАНИЧЕСКИХ СИСТЕМ
URL: https://rjmseer.com/0044-457X/article/view/665214
DOI: https://doi.org/10.31857/S0044457X23600524
EDN: https://elibrary.ru/HXWIDM
ID: 665214

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract

A spatial (3D) computer model of an isobaric phase diagram of the LiCl–PrCl3–KCl system was designed. The model was assembled of 66 surfaces and 27 phase regions, of which 31 surfaces and 14 phase regions degenerate to verticals or vertical planes because of the limited solubilities of the initial chlorides and their compounds. Published experimental isothermal sections and thermoanalytical curves for 33 salt melts were used to improve the quality of the 3D model. The results can be used to improve the molten-salt refining technology of nuclear fuel waste.

Keywords

phase diagram, computer simulation, 3D visualization, lithium chloride, praseodymium chloride, potassium chloride

References

Басин А.С., Каплун А.Б., Мешалкин А.Б. и др. // Журн. неорган. химии. 2008. Т. 53. № 9. С. 1611. https://doi.org/10.1134/S003602360809026X
Жемчужный С., Рамбах Ф. // Изв. С.-Петербург. политехн. ин-та. 1909. Т. 12. № 1. С. 349.
Elchardus E., Laffitte P. // Bull. Soc. Chim. Fr. 1932. V. 51. P. 1572.
Бухалова Г.А., Бурлакова В.М. // Журн. неорган. химии. 1966. Т. 11. С. 164.
Моисеенко Ж.Г., Акопов Е.К., Паниева Л.А. // Журн. неорган. химии. 1972. Т. 17. № 11. С. 3098.
Сафонов А.А., Труш Ф.Ф., Нахшин М.Ю. и др. // Журн. неорган. химии. 1983. Т. 28. С. 1344.
Бухалова Г.А., Ягубьян Е.С., Мирcоянова Н.Н. // Журн. неорган. химии. 1986. Т. 31. С. 279.
Korin E., Soifer L. // J. Therm. Anal. 1997. V. 50. P. 347.
Adachi A., Katayama Y., Miura T. et al. // J. Power Sources. 1997. V. 68. № 2. P. 348. https://doi.org/10.1016/S0378-7753(97)02587-1
Shirai O., Iizuka M., Iwai T. et al. // J. Electroanal. Chem. 2000. V. 490. P. 31. https://doi.org/10.1016/S0022-0728(00)00193-5
Laidler J.J., Battles J.E., Miller W.E. et al. // Prog. Nucl. Energy. 1997. V. 31. № 1–2. P. 131. https://doi.org/10.1016/0149-1970(96)00007-8
Masset P., Konings R.J.M., Malmbeck R. et al. // J. Nucl. Mater. 2005. V. 344. P. 173. https://doi.org/10.1016/j.jnucmat.2005.04.038
Murakami T., Rodrigues A., Ougier M. et al. // J. Nucl. Mater. 2015. V. 466. P. 502. https://doi.org/10.1016/j.jnucmat.2015.08.045
Gutknecht T.Y., Fredrickson G.L. Thermal Characterization of Molten Salt Systems. Idaho National Laboratory, 2011. 86 p.
Galashev A.Y. // Int. J. Energy Res. 2020. V. 45. № 8. P. 11459. https://doi.org/10.1002/er.6267
Ding L., Yan Y., Smolenski V. et al. // Sep. Purif. Technol. 2021. V. 279. P. 119683. https://doi.org/10.1016/j.seppur.2021.119683
Li Z., Tang D., Meng S. et al. // Sep. Purif. Technol. 2021. V. 276. P. 119045. https://doi.org/10.1016/j.seppur.2021.119045
Kim I.S., Okamoto Y. // Japan Atomic Energy Research Institute JAERI-Research 99-033. 1999. 16 p.
Qiao Z., Wang M., Zheng C. et al. // J. Chin. Rare Earth Soc. 1989. V. 7. P. 16.
Qiao Z., Wang M., Zheng C. et al. // Acta Metall. Sin. B. 1989. V. 25. P. 234.
Gong W., Gaune-Escard M., Rycerz L. // J. Alloys Compd. 2005. V. 396. P. 92. https://doi.org/10.1016/j.jallcom.2004.12.021
Ghosh S. Thermochemical Studies of Alloys and Molten Halide Salts of Relevance to Pyrochemical Reprocessing of Metallic Fuel. PhD, Diss. Kalpakkam, Tamil Nadu, India. 2016. 201 p.
Ghosh S., Ganesan R., Sridharan R. et al. // Thermochim. Acta. 2017. V. 653. P. 16. https://doi.org/10.1016/j.tca.2017.03.024
Seifert H.J., Sandrock J., Uebach J. // Z. Anorg. Allg. Chem. 1987. V. 555. P. 143. https://doi.org/10.1002/zaac.19875551215
Seifert H.J. // J. Therm. Anal. Calorim. 2002. V. 67. P. 789. https://doi.org/10.1023/A:1014341829611
Gaune-Escard M., Rycerz L., Szczepaniak W. et al. // J. Alloys Compd. 1994. V. 204. № 1–2. P. 189. https://doi.org/10.1016/0925-8388(94)90090-6
Nakamura K., Kurata M. // J. Nucl. Mater. 1997. V. 247. P. 309. https://doi.org/10.1016/S0022-3115(97)00099-8
Lutsyk V.I., Vorob’eva V.P. // J. Therm. Anal. Calorim. 2010. V. 101. № 1. P. 25. https://doi.org/10.1007/s10973-010-0855-0
Воробьева В.П., Зеленая А.Э., Луцык В.И. // Журн. неорган. химии. 2021. Т. 66. № 6. С. 798. https://doi.org/10.31857/S0044457X21060222
Lutsyk V.I., Zelenaya A.E., Zyryanov A.M. // J. Int. Sci. Publ.: Mater. Methods Technol. 2008. V. 2. P. 176.
Prince A. Alloy Phase Equilibria. Amsterdam–London–New York: Elsevier Publ. Comp., 1966. 290 p.
Райнз Ф. Диаграммы фазового равновесия в металлургии. М.: Гос. научно-технич. изд-во лит-ры по черной и цв. металлургии, 1960. 369 с.
Халдояниди К.А. Фазовые диаграммы гетерогенных систем с трансформациями. Новосибирск: ИНХ СО РАН, 2004. 382 с.