Complexes of Zinc Nitrate and Lanthanide Nitrates with Urea in the 1 : 2 Ratio

I. A. Karavaev; Караваев И. А.; E. V. Savinkina; Савинкина Е. В.; S. S. Ponkrashina; Понкрашина С. С.; M. S. Grigor’ev; Григорьев М. С.

doi:10.31857/S0044457X22601948

Complexes of Zinc Nitrate and Lanthanide Nitrates with Urea in the 1 : 2 Ratio

作者: Karavaev I.A.¹, Savinkina E.V.¹, Ponkrashina S.S.¹, Grigor’ev M.S.²
隶属关系:
1. Lomonosov Institute of Fine Chemical Technologies, MIREA—Russian Technological University
2. Frumkin Institute of Physical Chemistry and Electrochemistry
期: 卷 68, 编号 7 (2023)
页面: 923-929
栏目: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://rjmseer.com/0044-457X/article/view/665225
DOI: https://doi.org/10.31857/S0044457X22601948
EDN: https://elibrary.ru/RHLQQD
ID: 665225

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详细

Coordination compounds [Zn(H2O)4(Ur)2](NO3)2, [M(H2O)2(Ur)2(NO3)3] (M = Ce, Nd), and [Dy(H2O)(Ur)2(NO3)3] have been synthesized by the reaction of nitrates of zinc or rare earth elements with urea (Ur) in an aqueous solution. Their composition has been determined and structural features have been established using elemental analysis, IR spectroscopy, and X-ray diffraction analysis. For the zinc complex, a polymorphic transition has been found at 181 K.

关键词

nitrates of rare earth elements, urea, X-ray diffraction analysis, polymorphism

作者简介

I. Karavaev

Lomonosov Institute of Fine Chemical Technologies, MIREA—Russian Technological University

Email: savinkina@mirea.ru
119571, Moscow, Russia

E. Savinkina

Lomonosov Institute of Fine Chemical Technologies, MIREA—Russian Technological University

Email: savinkina@mirea.ru
119571, Moscow, Russia

S. Ponkrashina

Lomonosov Institute of Fine Chemical Technologies, MIREA—Russian Technological University

Email: savinkina@mirea.ru
119571, Moscow, Russia

M. Grigor’ev

Frumkin Institute of Physical Chemistry and Electrochemistry

编辑信件的主要联系方式.
Email: savinkina@mirea.ru
119071, Moscow, Russia

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