Synthesis and Structure of Trisubstituted closo-Decaborane [B10H7(1-IPh)(6(7),10-NHOCCH3)]: Specifics of Interaction between the [2-B10H9NH=C(OH)CH3]– Ion and PhI(OAc)2

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Abstract

The preparation of trisubstituted closo-decaboranes by reacting 1,2-boroxazoles with PhI(OAc)2 was studied. The process could be implemented in a one-pot variant proceeding from borylated iminol. The reaction products were characterized by 1H, 11B, and 13C NMR spectroscopy. The XRD structure of the compound [B10H7(1-IPh)(6,10-NHOCCH3)] was determined.

About the authors

V. V. Voinova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
119991, Moscow, Russia

N. A. Selivanov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
119991, Moscow, Russia

A. Yu. Bykov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
119991, Moscow, Russia

A. S. Kubasov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
119991, Moscow, Russia

A. P. Zhdanov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: golalekseival@mail.ru
119991, Moscow, Russia

K. Yu. Zhizhin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
119991, Moscow, Russia

N. T. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: zhdanov@igic.ras.ru
119991, Moscow, Russia

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Copyright (c) 2023 В.В. Воинова, Н.А. Селиванов, А.Ю. Быков, А.С. Кубасов, А.П. Жданов, К.Ю. Жижин, Н.Т. Кузнецов