Role of SiO2 in the Formation of Hydrate Phases in the Presence of СН4/CO2

Yu. Yu. Bozhko; Божко Ю. Ю.; R. K. Zhdanov; Жданов Р. К.; K. V. Gets; Гец К. В.; O. S. Subbotin; Субботин О. С.; V. R. Belosludov; Белослудов В. Р.

doi:10.31857/S0044457X22601572

Role of SiO2 in the Formation of Hydrate Phases in the Presence of СН4/CO2

Authors: Bozhko Y.Y.¹^,2, Zhdanov R.K.¹^,2, Gets K.V.¹^,2, Subbotin O.S.¹^,2, Belosludov V.R.¹^,2
Affiliations:
1. Novosibirsk State University
2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Issue: Vol 68, No 2 (2023)
Pages: 283-288
Section: НЕОРГАНИЧЕСКИЕ МАТЕРИАЛЫ И НАНОМАТЕРИАЛЫ
URL: https://rjmseer.com/0044-457X/article/view/665315
DOI: https://doi.org/10.31857/S0044457X22601572
EDN: https://elibrary.ru/LQYEIO
ID: 665315

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Abstract

The effect of silicon dioxide nanoparticles on the formation of hydrate phases in the presence of CH4/CO2 has been studied. The theoretical experiment has been carried out by molecular dynamics methods at initial pressures in the system of 2.4 and 1.2 MPa and a temperature of 271 K for methane and carbon dioxide systems. The results showed that in the presence of silicon dioxide nanoparticles, the induction time of the methane hydrate formation decreased by 79%, and the amount of methane trapped in the hydrate cavity increased by 55.8% at a pressure of 2.4 MPa. In the presence of silicon dioxide nanoparticles, the induction time for the formation of carbon dioxide hydrate decreased by 62%, and the amount of carbon dioxide trapped in the hydrate cavity increased by 27.8% at a pressure of 1.2 MPa.

Keywords

gas hydrates, nanoparticles, molecular dynamics, computer modeling, greenhouse gases

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