Oxidative Dehydrogenation of Ethane on Oxide-Supported Vanadium Phosphorus Oxide Catalysts

A. A. Malygin; Малыгин А. А.; A. B. Yaroslavtsev; Ярославцев А. Б.; N. A. Zhilyaeva; Жиляева Н. А.; V. I. Elizarova; Елизарова В. И.; E. Yu. Mironova; Миронова Е. Ю.; A. A. Malkov; Малков А. А.; I. S. Bodalyov; Бодалёв И. С.

doi:10.31857/S0044457X22600918

Oxidative Dehydrogenation of Ethane on Oxide-Supported Vanadium Phosphorus Oxide Catalysts

Authors: Malygin A.A.¹, Yaroslavtsev A.B.²^,3, Zhilyaeva N.A.², Elizarova V.I.², Mironova E.Y.², Malkov A.A.¹, Bodalyov I.S.¹
Affiliations:
1. Saint Petersburg State Institute of Technology
2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Issue: Vol 68, No 1 (2023)
Pages: 96-104
Section: НЕОРГАНИЧЕСКИЕ МАТЕРИАЛЫ И НАНОМАТЕРИАЛЫ
URL: https://rjmseer.com/0044-457X/article/view/665333
DOI: https://doi.org/10.31857/S0044457X22600918
EDN: https://elibrary.ru/GVDJNL
ID: 665333

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Abstract

Comparative results of studying the oxidative dehydrogenation of ethane (ODE) on catalytic vanadium-phosphorus oxide systems deposited by the molecular layering method on the surface of oxide supports (Al2O3, SiO2) have been presented. It has been found that the highest activity in ODE and selectivity for ethylene are exhibited by vanadium-phosphorus-containing catalysts. The influence of the acidity of catalytic systems on the activity and selectivity of the process has been revealed. The selectivity of the ODE process for ethylene reaches 90%. An increase in the oxygen concentration in the initial mixture from 3.5 to 20% leads mainly to a decrease in the selectivity of the ODE process with respect to the ethylene yield.

Keywords

oxidative dehydrogenation, ethane, ethylene, vanadium phosphorus oxide systems, molecular layering

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