Vanishing Superstructure: Crystal and Local Structures of Ni3 – xMTe2 (M = Sb, Sn)

E. A. Stroganova; Строганова Е. А.; S. M. Kazakov; Казаков С. М.; P. B. Fabrichnii; Фабричный П. Б.; M. I. Afanasov; Афанасов М. И.; A. N. Kuznetsov; Кузнецов А. Н.

doi:10.31857/S0044457X23601529

Vanishing Superstructure: Crystal and Local Structures of Ni3 – xMTe2 (M = Sb, Sn)

Authors: Stroganova E.A.¹, Kazakov S.M.¹, Fabrichnii P.B.¹, Afanasov M.I.¹, Kuznetsov A.N.¹
Affiliations:
1. Faculty of Chemistry, Moscow State University
Issue: Vol 68, No 12 (2023)
Pages: 1691-1701
Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://rjmseer.com/0044-457X/article/view/666031
DOI: https://doi.org/10.31857/S0044457X23601529
EDN: https://elibrary.ru/RJZGNB
ID: 666031

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Abstract

Series of compounds Ni3 – xMTe2 (M = Sb, Sn; x = 0–1) were obtained by high-temperature sealed-tube synthesis and characterized by X-ray powder diffraction and 121Sb and 119Sn Mössbauer spectroscopy. For Ni3–xSnTe2, it was shown that, as х varies from 1 to 0, nickel is distributed over three possible sites, two of which give a total occupancy of 1 and have ordered vacancies. Meanwhile, for Ni3–xSbTe2 and х other than ~0.9–1.0, the vacancy ordering disappears. The temperature dependence of the presence or absence of vacancy ordering was established for Ni2SbTe2; the ordering disappears on heating above 600°C and appears again on cooling.

Keywords

layered phases, nickel tellurides, heterometallic bonds, solid state synthesis, X-ray powder, diffraction, Mössbauer spectroscopy

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