Thermochemical Study of Bismuth Cobalt Dysprosium Oxide: The Enthalpy of Formation and Lattice Enthalpy

N. I. Matskevich; Мацкевич Н. И.; A. N. Semerikova; Семерикова А. Н.; N. V. Gel’fond; Гельфонд Н. В.; V. P. Zaitsev; Зайцев В. П.; M. Yu. Matskevich; Мацкевич М. Ю.; O. I. Anufrieva; Ануфриева О. И.; A. A. Fedorov; Федоров А. А.

doi:10.31857/S0044457X23601402

Thermochemical Study of Bismuth Cobalt Dysprosium Oxide: The Enthalpy of Formation and Lattice Enthalpy

Authors: Matskevich N.I.¹, Semerikova A.N.¹, Gel’fond N.V.¹, Zaitsev V.P.¹^,2, Matskevich M.Y.¹, Anufrieva O.I.¹, Fedorov A.A.¹
Affiliations:
1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
2. Siberian State University of Water Transport
Issue: Vol 68, No 12 (2023)
Pages: 1786-1791
Section: ФИЗИКО-ХИМИЧЕСКИЙ АНАЛИЗ НЕОРГАНИЧЕСКИХ СИСТЕМ
URL: https://rjmseer.com/0044-457X/article/view/666073
DOI: https://doi.org/10.31857/S0044457X23601402
EDN: https://elibrary.ru/BWNIYL
ID: 666073

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Abstract

Bismuth cobalt dysprosium oxide of composition Bi12.5Dy1.5CoO22.325 has been prepared by solid-state reactions. The compound has a cubic structure (space group Fm
m) with the unit cell parameter a = 0.55279(5) nm. The solution enthalpy and standard enthalpy of formation of Bi12.5Dy1.5CoO22.325 have been measured by solution calorimetry: ΔsolH0 = −1017.0 ± 7.5 kJ/mol, and ΔfH0 = −5338.8 ± 19.9 kJ/mol. The lattice enthalpy has been calculated using the Born–Haber cycle: ΔlatH0 = −99020 kJ/mol. The lattice enthalpy increases in magnitude as the lanthanide radius decreases in the neodymium–dysprosium–holmium series.

Keywords

bismuth oxide, cobalt oxide, dysprosium oxide, enthalpy of formation, lattice enthalpy

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