Solubilities of Components in the Сa(ClO3)2∙NH4Сl–H2O System

O. O. Rakhmonov; Рахмонов О. О.; A. A. Sidikov; Сидиков А. А.; Zh. S. Shukurov; Шукуров Ж. С.; A. S. Togasharov; Тогашаров А. С.

doi:10.31857/S0044457X23601244

Solubilities of Components in the Сa(ClO3)2∙NH4Сl–H2O System

Authors: Rakhmonov O.O.¹, Sidikov A.A.¹, Shukurov Z.S.¹, Togasharov A.S.¹
Affiliations:
1. Institute of General and Inorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan
Issue: Vol 68, No 12 (2023)
Pages: 1811-1815
Section: ФИЗИКО-ХИМИЧЕСКИЙ АНАЛИЗ НЕОРГАНИЧЕСКИХ СИСТЕМ
URL: https://rjmseer.com/0044-457X/article/view/666090
DOI: https://doi.org/10.31857/S0044457X23601244
EDN: https://elibrary.ru/HUISJQ
ID: 666090

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Abstract

The Сa(ClO3)2∙NH4Сl–H2O system has been studied in its constituent binary systems and seven inner sections, and its polythermal solubility diagram has been plotted in the range of temperatures from–42.5 to 87.5°С. The solubility diagram features the crystallization fields of ice; calcium chlorate hexahydrate, tetrahydrate, and dihydrate; and ammonium chloride. Three ternary points exist in the system. The system belongs to the complex eutonic type; its components retain their individuality and show good solubility in water. In the [40% Сa(ClO3)2 + 60% H2O]–[NH4Сl] section of the studied system, variations in crystallization temperature, viscosity, density, pH, and refractive indices of the solution have been determined. The thus-obtained results have been used to plot the composition–property diagram of the [40% Сa(ClO3)2 + 60% H2O]–[NH4Сl] section of the Сa(ClO3)2∙NH4Сl–H2O system.

Keywords

calcium chlorate, ammonium chloride, solubility, diagram, composition–property

References

Li S., Liu R., Wang X. et al. // J. Plant Growth Regul. 2021. V. 40. P. 1667. https://doi.org/10.1007/s00344-020-10218-w
Botirova M.I., Ibragimova D.M. Modern Defoliants. N.Y., 2022. https://conferencea.org/index.php/conferences/article/view/1602
Leon R., David L.W., Barry J.B. // EDIS. 2013. V. 9. https://doi.org/10.32473/edis-ag188-2013
https://edis.ifas.ufl.edu/publication/AG188#FOOTNOTE_1
Sidikova A.A., Toghasharova A.S., Shukurova J.S. // Russ. J. Inorg. Chem. 2021. V. 66. P. 1554. https://doi.org/10.1134/S003602362110017X
Pedersen M.K., Burton J.D., Coble H.D. // Crop. Sci. 2006. V. 46. P. 1666. https://doi.org/10.2135/cropsci2005.07-0189
Умаров А.А., Кутянин Л.И. Новые дефолианты: поиск, свойства, применения. М.: Химия, 2000. 142 с.
Amarapalli G., Bhavya K., Saidaiah P. Advances in genetics and plant breeding. New Delhi: AkiNik Publications, 2021. 81 p.
Назаров Р. // Журн. с.-хоз. Узб. 2003. № 8. С. 12.
Xiaojing W., Sijia L., Ruixian L. et al. // Cot. Scien. 2019. V. 31. P. 64. https://doi.org/10.11963/1002-7807.wxjlrx.20181228
Turayev K.A., Togasharov A.S., Tukhtaev S. // J. Chem. Technol. Metall. 2022. V. 57. P. 977.
Karademir E., Karademir C., Basbag S. // J. Cent. Eur. Agric. 2007. V. 8. P. 8.
Faircloth J.C., Edmisten K.L., Wells R., Stewart A.M. // Crop Science. 2004. V. 44. P. 165.
Shukurov Z.S., Khusanov E.S., Mukhitdinova M.S., Togasharov A.S. // Russ. J. Inorg. Chem. 2021. V. 66. P. 902. https://doi.org/10.1134/S0036023621060176
Iboyi J.E., Mulvaney M.J., Bashyal M. et al. // EDIS. 2021. V. 6. https://doi.org/10.32473/edis-pi138-2021
Hamai M., Mogi I., Tagami M. et al. // J. Cryst. Growth. 2000. V. 209. P. 1013.
Сессиек П., Груй Ф., Курнил М. // Журн. роста крист. 2000. Т. 208. С. 555.
Tuychiev S.A., Sidikov A.A., Togasharov A.S. et al. // Russ. J. Inorg. Chem. 2022. V. 67. Suppl. 2. P. S184. https://doi.org/10.1134/S0036023622602112
Мельников Н.Н., Новожилов К.В., Белан С.Р., Пылова Т.Н. Справочник по пестицидам. М.: Химия, 1985. 352 с.
Набеева Р.А. Влияние предпосевных обработок солями 1,3-аминосульфидов и n,n-бис(диметиламинометил)–тиомочевиной на физиолого-биохимические процессы растений пшеницы: дис. … канд. биол. наук. Уфа, 2016. 162 с.
Мельников Н.Н. Новые пестициды. М.: Мир, 1964. 319 с.
Bobozhonov Zh., Shukurov Zh., Togasharov A., Akhmadzhonova M. // Russ. J. Inorg. Chem. 2021. V. 66. P. 1031. https://doi.org/10.1134/S0036023621070032
Шварценбах Г., Флашка Г. Комплексонометрическое титрование / Пер. с нем. под ред. Вайнштейн Ю.И. М.: Химия, 1970. 360 с.
Крешков А.П. Основы аналитической химии. М.: Химия, 1965. 376 с.
Климова В.А. Основные микрометоды анализа органических соединений. М.: Химия, 1975. 224 с.
Трунин А.С., Петрова Д.Г. Визуально-политермический метод. Куйбышев, 1977. 93 с.
Здановский А.Б. Галургия. М.: Химия, 1972. 528 с.