Zirconium (Hafnium)-Containing Yttriumoxane Alumoxanes and Multicomponent Ceramics Based on Them

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Abstract

Ceramic-forming zirconium (hafnium)-containing yttriumoxane alumoxanes, precursors of multicomponent ceramics based on alumina, yttria and zirconia/hafnia, were synthesized by co-condensation of chelated alkoxyalumoxanes, yttrium acetylacetonate hydrate (or organic yttriumoxane alumoxanes) and zirconium or hafnium acetylacetonate. The physicochemical properties of zirconium (hafnium)-containing yttriumoxane alumoxanes were studied. Computational models of the group and elemental composition of oligomeric Zr(Hf)-containing yttriumoxane alumoxane molecules were proposed. According to X-ray diffraction and scanning electron microscopy data, pyrolysis of the oligomers at 1500–1600°C results in multicomponent nano- or fine-crystalline ceramic powders, depending on the Al/Y and Al/Zr(Hf) molar ratios.

About the authors

G. I. Shcherbakova

State Research Institute for Chemistry and Technology of Organoelement Compounds

Email: galina7479@mail.ru
105118, Moscow, Russia

A. S. Pokhorenko

State Research Institute for Chemistry and Technology of Organoelement Compounds

Email: galina7479@mail.ru
105118, Moscow, Russia

N. S. Krivtsova

State Research Institute for Chemistry and Technology of Organoelement Compounds

Email: galina7479@mail.ru
105118, Moscow, Russia

M. S. Varfolomeev

State Research Institute for Chemistry and Technology of Organoelement Compounds; Moscow Aviation Institute (National Research University)

Email: galina7479@mail.ru
105118, Moscow, Russia; 125080, Moscow, Russia

A. I. Drachev

State Research Institute for Chemistry and Technology of Organoelement Compounds

Email: galina7479@mail.ru
105118, Moscow, Russia

Yu. B. Lebed

State Research Institute for Chemistry and Technology of Organoelement Compounds; Institute for Nuclear Research, Russian Academy of Sciences

Email: galina7479@mail.ru
105118, Moscow, Russia; 117312, Moscow, Russia

A. A. Ashmarin

Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences

Email: galina7479@mail.ru
119334, Moscow, Russia

T. L. Apuhtina

State Research Institute for Chemistry and Technology of Organoelement Compounds

Email: galina7479@mail.ru
105118, Moscow, Russia

A. E. Chernyshev

State Research Institute for Chemistry and Technology of Organoelement Compounds

Email: galina7479@mail.ru
105118, Moscow, Russia

P. A. Storozhenko

State Research Institute for Chemistry and Technology of Organoelement Compounds

Author for correspondence.
Email: galina7479@mail.ru
105118, Moscow, Russia

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Copyright (c) 2023 Г.И. Щербакова, А.С. Похоренко, Н.С. Кривцова, М.С. Варфоломеев, А.И. Драчев, Ю.Б. Лебедь, А.А. Ашмарин, Т.Л. Апухтина, А.Е. Чернышев, П.А. Стороженко