Thermophysical Properties of Neodymium and Gadolinium Zirconate Hafnates

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Abstract

Pyrochlore-type neodymium and gadolinium zirconate hafnates have been prepared and identified. The heat capacities of the prepared samples have been measured by differential scanning calorimetry in the range 310–1800 K. Temperature-dependent cubic unit cell parameters have been determined and thermal expansion coefficients assessed in the range 298–1273 K using high-temperature X-ray diffraction. The thermal diffusivity of the samples was measured by the laser flash method, and the temperature-dependent thermal conductivity was calculated taking into account the porosity of the samples.

About the authors

P. G. Gagarin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: gagarin@igic.ras.ru
119991, Moscow, Russia

A. V. Guskov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: gagarin@igic.ras.ru
119991, Moscow, Russia

V. N. Guskov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: gagarin@igic.ras.ru
119991, Moscow, Russia

A. V. Khoroshilov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: gagarin@igic.ras.ru
119991, Moscow, Russia

K. S. Gavrichev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: gagarin@igic.ras.ru
119991, Moscow, Russia

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Copyright (c) 2023 П.Г. Гагарин, А.В. Гуськов, В.Н. Гуськов, А.В. Хорошилов, К.С. Гавричев