Copper(II) Catecholate Complexes with Polypyridyl Ligands

O. Yu. Trofimova; Трофимова О. Ю.; K. I. Pashanova; Пашанова К. И.; I. V. Ershova; Ершова И. В.; M. V. Arseniev; Арсеньев М. В.; I. A. Yakushev; Якушев И. А.; P. V. Dorovatovsky; Дороватовский П. В.; R. R. Aisin; Айсин Р. Р.; A. V. Piskunov; Пискунов А. В.

doi:10.31857/S0044457X23600846

Copper(II) Catecholate Complexes with Polypyridyl Ligands

Authors: Trofimova O.Y.¹, Pashanova K.I.¹, Ershova I.V.¹, Arseniev M.V.¹, Yakushev I.A.², Dorovatovsky P.V.³, Aisin R.R.⁴, Piskunov A.V.¹
Affiliations:
1. Rasuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
3. National Research Center “Kurchatov Institute”
4. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Issue: Vol 68, No 9 (2023)
Pages: 1154-1164
Section: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://rjmseer.com/0044-457X/article/view/666209
DOI: https://doi.org/10.31857/S0044457X23600846
EDN: https://elibrary.ru/YIEZEI
ID: 666209

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Abstract

Copper(II) catecholate complexes based on 3,6-di-tert-butyl-o-benzoquinone with N-donor ligands of the phenanthroline series have been synthesized: (3,6-Cat)Cu(Phen) (I), (3,6-Cat)Cu(DPQ) (II), and (3,6-Cat)Cu(DPPZ) (III), where 3,6-Cat is the 3,6-di-tert-butyl-o-benzoquinone dianion, Phen is phenanthroline, DPQ is dipyrido[3,2-d:2',3'-f]quinoxaline, and DPPZ is dipyrido[3,2-a:2',3'-c]phenazine. The synthesized copper(II) complexes demonstrate intramolecular ligand-to-ligand charge transfer responsible for their intense violet color. The electronic structure of the synthesized chromophores was studied by electronic spectroscopy, cyclic voltammetry, and quantum-chemical calculations. The molecular and crystal structures of the synthesized compounds were determined by X-ray diffraction analysis (CIF files CCDC 2 250 975 (I⋅THF), 2 250 976 ([(II⋅THF)(II)]⋅3THF), 2250977 (II)).

Keywords

copper, redox-active ligand, catecholate, phenanthroline, charge transfer, electronic, spectroscopy, cyclic voltammetry, single crystal X-ray diffraction

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