Synthesis of C-mercuro derivatives of ortho-carborane. Crystal structure of bis(2-phenyl-ortho-carboran-1-yl)mercury

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Abstract

Many carborane derivatives, first synthesized during the rapid development of this field of chemistry in the 60s of the last century, remained completely uncharacterized by modern spectral and structural methods. In this work, a series of C-mercuro derivatives of ortho-carborane 1-PhHg-2-Ph-1,2-C2B10H10 and (2-R-1,2-C2B10H10)2Hg (R = H, Me, Ph) were newly synthesized and characterized by NMR spectroscopy. The molecular crystal structure of bis(2-phenyl-ortho-carboran-1-yl)mercury was determined by single crystal X-ray diffraction.

About the authors

S. А. Anufriev

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: sivaev@ineos.ac.ru
Russian Federation, Moscow

S. V. Timofeev

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: sivaev@ineos.ac.ru
Russian Federation, Moscow

D. I. Nasyrova

Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences; Moscow Institute of Physics and Technology

Email: sivaev@ineos.ac.ru
Russian Federation, Moscow; Dolgoprudny

I. B. Sivaev

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Plekhanov Russian University of Economics

Author for correspondence.
Email: sivaev@ineos.ac.ru
Russian Federation, Moscow; Moscow

V. I. Bregadze

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: sivaev@ineos.ac.ru
Russian Federation, Moscow

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Посвящается 125-летию со дня рождения академика А.Н. Несмеянова и 70-летию основания Института элементоорганических соединений Российской академии наук.


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