Estimated hansen solubility parameters of low-dimensional vanadium, niobium and tantalum dichalcogenides

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Abstract

Low-dimensional flakes of transitional metal dichalcogenides TaX2 (X = S, Se, Te), VSe2 and NbSe2 were acquired using liquid-phase exfoliation process. Hansen solubility parameters of those dispersions were estimated by measuring extinction in a number of various liquid environments. Amount of low-dimensional particles of dichalcogenides in a sample increases with decrease of Hansen distance between dichalcogenide and exfoliation medium. We propose a method to qualitatively estimate the impact exfoliation medium has on the size of forming particles and demonstrate how decrease of the absolute value of δpolar and δhydrogen in examined systems leads to decrease in size of forming flakes.

About the authors

К. S. Nikonov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Author for correspondence.
Email: nikonovk.s@yandex.ru
Russian Federation, Moscow

Т. К. Menshikova

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: nikonovk.s@yandex.ru
Russian Federation, Moscow

М. N. Brekhovskikh

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: nikonovk.s@yandex.ru
Russian Federation, Moscow

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