Synthesis and properties of LiNiO2 close to stoichiometric composition obtained by combined synthesis method

Capa

Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Acesso é pago ou somente para assinantes

Resumo

This study presents the synthesis and characterisation of lithium nickelate LiNiO₂ with near-stoichiometric composition prepared by a combined method. LiNiO2 exhibits high electrochemical properties including a theoretical capacity of 250–270 mA/g, making it a promising cathode material for lithium-ion batteries as an alternative to LiCoO2. However, the commercial use of LiNiO₂ is limited by the difficulty in achieving stoichiometric composition and the high cost of conventional synthesis methods. Using X-ray phase analysis and spectrometry, we identified the phases formed and determined their chemical composition. Electron microscopy and Brunauer-Emmett-Teller (BET) techniques were used to investigate the structure and morphology. The developed process scheme led to the preparation of lithium nickelate with the composition Li(0.98)Ni(1.02)O₂, providing the formation of nanoscale samples with high specific surface area and improved electrochemical performance. These results emphasise the potential of LiNiO2 as a competitive cathode material for lithium-ion batteries.

Texto integral

Acesso é fechado

Sobre autores

R. Korneykov

Sakhalin State University; Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials

Autor responsável pela correspondência
Email: v.efremov@ksc.ru

Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials

Rússia, Yuzhno-Sakhalinsk, 693000; Apatity, 184209

V. Efremov

Sakhalin State University; Institute of Industrial Problems of the North Ecology

Email: v.efremov@ksc.ru
Rússia, Yuzhno-Sakhalinsk, 693000; Apatity, 184209

S. Aksenova

Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials

Email: v.efremov@ksc.ru

Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials

Rússia, Apatity, 184209

K. Kesarev

Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials

Email: v.efremov@ksc.ru

Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials

Rússia, Apatity, 184209

O. Akhmetov

Sakhalin State University

Email: v.efremov@ksc.ru
Rússia, Yuzhno-Sakhalinsk, 693000

O. Shcherbina

Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials

Email: v.efremov@ksc.ru

Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials

Rússia, Apatity, 184209

I. Elyzarova

Institute of Industrial Problems of the North Ecology

Email: v.efremov@ksc.ru
Rússia, Apatity, 184209

I. Tananaev

Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials

Email: v.efremov@ksc.ru

Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials

Rússia, Apatity, 184209

O. Shichalin

Sakhalin State University

Email: v.efremov@ksc.ru
Rússia, Yuzhno-Sakhalinsk, 693000

Bibliografia

  1. Collins D.H. // J. Power Sources. 1994. V. 52. № 2. P. 313. https://doi.org/10.1016/0378-7753(94)87026-8
  2. Ohzuku T., Ueda A., Nagayama M. // J. Electrochem. Soc. 1993. V. 140. № 7. P. 1862. https://doi.org/10.1149/1.2220730
  3. Kalaiselvi N., Periasamy P., Thirunakaran R. et al. // Ionics (Kiel). 2001. V. 7. № 4–6. P. 451. https://doi.org/10.1007/BF02373583
  4. Minakshi M., Sharma N., Ralph D. et al. // Electrochem. Solid-State Lett. 2011. V. 14. № 6. P. A86. https://doi.org/10.1149/1.3561764
  5. Divakaran A.M., Minakshi M., Bahri P.A. et al. // Prog. Solid State Chem. 2021. V. 62. P. 100298. https://doi.org/10.1016/j.progsolidstchem.2020.100298
  6. Wang R.-C., Lin Y.-C., Wu S.-H. // Hydrometallurgy. 2009. V. 99. № 3–4. P. 194. https://doi.org/10.1016/j.hydromet.2009.08.005
  7. Monajjemi M., Mollaamin F., Thu P.T. et al. // Russ. J. Electrochem. 2020. V. 56. № 8. P. 669. https://doi.org/10.1134/S1023193520030076
  8. Sivajee Ganesh K., Purusottam Reddy B., Jeevan Kumar P. et al. // J. Electroanal. Chem. 2018. V. 828. P. 71. https://doi.org/10.1016/j.jelechem.2018.09.032
  9. Kalyani P. // J. Power Sources. 2002. V. 111. № 2. P. 232. https://doi.org/10.1016/S0378-7753(02)00307-5
  10. Ramesh Babu B., Periasamy P., Thirunakaran R. et al. // Int. J. Inorg. Mater. 2001. V. 3. № 4–5. P. 401. https://doi.org/10.1016/S1466-6049(01)00023-X
  11. Thirunakaran R., Kalaiselvi N., Periasamy P. et al. // Ionics (Kiel). 2001. V. 7. № 3. P. 187. https://doi.org/10.1007/BF02419227
  12. Bianchini M., Roca‐Ayats M., Hartmann P. et al. // Angew. Chem. Int. Ed. 2019. V. 58. № 31. P. 10434. https://doi.org/10.1002/anie.201812472
  13. Hata M., Tanaka T., Kato D. et al. // Electrochem. 2021. V. 89. № 3. P. 223. https://doi.org/10.5796/electrochemistry.20-65151
  14. Tolganbek N., Yerkinbekova Y., Kalybekkyzy S. et al. // J. Alloys Compd. 2021. V. 882. P. 160774. https://doi.org/10.1016/j.jallcom.2021.160774
  15. Shembelʹ E.M., Apostolova R.D., Aurbach D. et al. // Russ. J. App. Chem. 2014. V. 87. № 9. P. 1260. https://doi.org/10.1134/S1070427214090122
  16. Wang L., Chen B., Ma J. et al. // Chem. Soc. Rev. 2018. V. 47. № 17. P. 6505. https://doi.org/10.1039/C8CS00322J
  17. Divakaran A.M., Minakshi M., Bahri P.A. et al. // Prog. Solid State Chem. 2021. V. 62. P. 100298. https://doi.org/10.1016/j.progsolidstchem.2020.100298
  18. Kalyani P., Kalaiselvi N. // Sci. Technol. Adv. Mater. 2005. V. 6. № 6. P. 689. https://doi.org/10.1016/j.stam.2005.06.001
  19. Kalyani P., Kalaiselvi N., Renganathan N.G. // J. Power Sources. 2003. V. 123. № 1. P. 53. https://doi.org/10.1016/S0378-7753(03)00458-0
  20. Kalyani P., Kalaiselvi N., Renganathan N.G. et al. // Mater. Res. Bull. 2004. V. 39. № 1. P. 41. https://doi.org/10.1016/j.materresbull.2003.09.021
  21. Mesnier A., Manthiram A. // ACS Appl. Mater. Interfaces. 2020. V. 12. № 47. P. 52826. https://doi.org/10.1021/acsami.0c16648
  22. Välikangas J., Laine P., Hietaniemi M. et al. // Appl. Sci. 2020. V. 10. № 24. P. 8988. https://doi.org/10.3390/app10248988
  23. Bianchini M., Fauth F., Hartmann P. et al. // J. Mater. Chem. A. Mater. 2020. V. 8. № 4. P. 1808. https://doi.org/10.1039/C9TA12073D
  24. Pesterfield L. // J. Chem. Educ. 2009. V. 86. № 10. P. 1182. https://doi.org/10.1021/ed086p1182
  25. Tretyakov Yu.D., Martynenko L.I., Grigoriev A.N., Tsivadze A.Yu. // Inorg. Сhem. 2001. V. 1. Р. 378.
  26. Makhonina E.V., Pervov V.S., Dubasova V.S. // Russ. Chem. Rev. 2004. V. 73. № 10. P. 991. https://doi.org/10.1070/RC2004v073n10ABEH000896
  27. Рабинович В.А., Хавик Э.Я. Краткий химический справочник. Л.: Химия, 1978. 334 с.
  28. Riewald F., Kurzhals P., Bianchini M. et al. // J. Electrochem. Soc. 2022. V. 169. № 2. P. 020529. https://doi.org/10.1149/1945-7111/ac4bf3
  29. Taha T.A., El-Molla M.M. // J. Mater. Res.Technol. 2020. V. 9. № 4. P. 7955. https://doi.org/10.1016/j.jmrt.2020.04.098
  30. Yan F.Y., Zhang H., Lai Q. // J. Sichuan University. 2002. V. 39. P. 918.
  31. Ohzuku T., Ueda A., Nagayama M. et al. // Electrochim. Acta. 1993. V. 38. № 9. P. 1159. https://doi.org/10.1016/0013-4686(93)80046-3
  32. Taha T.A., Elrabaie S., Attia M.T. // J. Mater. Sci.: Mater. Electron 2018. V. 29. № 21. P. 18493. https://doi.org/10.1007/s10854-018-9965-4
  33. Levi M.D., Aurbach D. // J. Phys. Chem. B. 2004. V. 108. № 31. P. 11693. https://doi.org/10.1021/jp0486402
  34. Umeda M., Dokko K., Fujita Y. et al. // Electrochim. Acta. 2001. V. 47. № 6. P. 885. https://doi.org/10.1016/S0013-4686(01)00799-X
  35. Wang C., Appleby A.J., Little F.E. // Electrochim. Acta. 2001. V. 46. № 12. P. 1793. https://doi.org/10.1016/S0013-4686(00)00782-9
  36. Ivanishchev A.V., Gridina N.A., Rybakov K.S. et al. // J. Electroanal. Chem. 2020. V. 860. P. 113894. https://doi.org/10.1016/j.jelechem.2020.113894
  37. Чуриков А.В., Иванищев А.В., Запсис К.В. и др. // Электрохим. энергетика. 2007. T. 7. № 4. С. 169.
  38. Amin R., Ravnsbæk D.B., Chiang Y.-M. // J. Electrochem. Soc. 2015. V. 162. № 7. P. A1163. https://doi.org/10.1149/2.0171507jes

Arquivos suplementares

Arquivos suplementares
Ação
1. JATS XML
Baixar
2. Fig. 1. X-ray diffraction patterns of samples: a – Li0.25Ni1.75O2, b – Li0.35Ni1.65O2, c – Li0.64Ni1.36O2, d – Li0.98Ni1.02O2, d – Li0.524Ni1.476O2, e – Li0.79Ni1.21O2, g – Li0.92Ni1.08O2, h – Li0.55Ni1.45O2, i – Li0.68Ni1.32O2, k – Li0.75Ni1.25O2.

Baixar (363KB)
Metadados
3. Fig. 2. IR spectrum of the sample with the composition Li0.98Ni1.02O2.

Baixar (59KB)
Metadados
4. Fig. 3. Schematic flow chart for obtaining lithium nickelate

Baixar (251KB)
Metadados
5. Fig. 4. SEM images of samples, Li0.79Ni1.21O2 (a) and Li0.98Ni1.02O2 (b).

Baixar (1011KB)
Metadados
6. Fig. 5. Complex impedance diagram of Li0.79Ni1.21O2.

Baixar (56KB)
Metadados
7. Fig. 6. Complex impedance diagram of Li0.98Ni1.02O2.

Baixar (61KB)
Metadados
8. Fig. 7. Equivalent equivalent circuit.

Baixar (44KB)
Metadados

Declaração de direitos autorais © Russian Academy of Sciences, 2025