Morphology and luminescent properties of nanocrystalline NaGdF4 phosphors doped with neodymium(III) ions

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Abstract

Nanocrystalline phosphors NaGd1- x Nd x F4 ( x = 0-1) were synthesized by hydrothermal synthesis for the first time. All the synthesized compounds have hexagonal β-NaYF4 crystalline phase. Neodymium(III) ions isomorphically replace gadolinium ions. NaGd0.96Nd0.04F4 compound has the largest photoemission intensity in NIR range upon 808 nm excitation; further doping with Nd3+ results in concentration quenching.

About the authors

A. A Betina

St. Petersburg State University

T. S Bulatova

St. Petersburg State University

V. G Nosov

St. Petersburg State University

I. E Kolesnikov

St. Petersburg State University

N. A Bogachev

St. Petersburg State University

M. Yu. Skripkin

St. Petersburg State University

A. S Mereshchenko

St. Petersburg State University

Email: a.mereshchenko@spbu.ru

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