Quaternization of Methyl Picolinate with Some Phenacyl Bromides. Synthesis of DL-Baikiain Alkaloid

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By fusing methyl picolinate with phenacyl bromides, the corresponding phenacyl salts were obtained, cyclization of which in acetic anhydride led to previously undescribed 3-aryl-1H-pyrido[2,1-c][1,4]oxazinium bromides. Reduction of the quaternary salts of methyl picolinate followed by acid hydrolysis leads to the alkaloid DL-baikiain.

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作者简介

D. Lomov

L. M. Litvinenko Institute of Physical Organic and Coal Chemistry

编辑信件的主要联系方式.
Email: lomov_dmitrii@mail.ru
俄罗斯联邦, Donetsk

M. Abramyants

L. M. Litvinenko Institute of Physical Organic and Coal Chemistry

Email: lomov_dmitrii@mail.ru
俄罗斯联邦, Donetsk

O. Zaporozhets

L. M. Litvinenko Institute of Physical Organic and Coal Chemistry

Email: lomov_dmitrii@mail.ru
俄罗斯联邦, Donetsk

T. Pekhtereva

L. M. Litvinenko Institute of Physical Organic and Coal Chemistry

Email: lomov_dmitrii@mail.ru
俄罗斯联邦, Donetsk

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