Thermal Behavior (–180 ≤ T ≤ 1000°C) of Magnesium Orthosilicate Hydroxylclinohumite Mg5(SiO4)2(OH,F)2

Ya. P. Biryukov; Бирюков Я. П.; R. S. Bubnova; Бубнова Р. С.; V. A. Firsova; Фирсова В. А.

doi:10.31857/S0132665122600716

Thermal Behavior (–180 ≤ T ≤ 1000°C) of Magnesium Orthosilicate Hydroxylclinohumite Mg5(SiO4)2(OH,F)2

Authors: Biryukov Y.P.¹, Bubnova R.S.¹^,2, Firsova V.A.¹
Affiliations:
1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences
2. St. Petersburg State University
Issue: Vol 49, No 2 (2023)
Pages: 209-216
Section: КРАТКОЕ СООБЩЕНИЕ
URL: https://rjmseer.com/0132-6651/article/view/663262
DOI: https://doi.org/10.31857/S0132665122600716
EDN: https://elibrary.ru/NVDPWQ
ID: 663262

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription or Fee Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

Hydroxylclinohumite Mg5(SiO4)2(OH,F)2 is a common monoclinic orthosilicate of the humite group, which, on the one hand, is a prototype of promising materials, and, on the other hand, is an important source of information about both the transport and the presence of water in the Earth’s mantle, and therefore studying its thermal behavior is of particular interest. In this paper, the mineral is studied by powder X-ray diffraction for the first time in a wide temperature range (–180 ≤ T ≤ 1000°C). The temperature limits for the existence of the phase are established, the principal values of the thermal expansion tensor are calculated, and a structural interpretation of thermal expansion is given.

Keywords

magnesium silicate, hydroxylclinohumite, humite, crystal structure, thermal expansion, low- and high-temperature X-ray powder diffraction

References

Geijer P. Norbergite and Fluoborite, two new minerals from the Norberg mining district // Geologiska Föreningen i Stockholm Förhandlingar. 1926. V. 48(1). P. 84–85.
Berry A.J., James M. Refinement of hydrogen positions in natural chondrodite by powder neutron diffraction: implications for the stability of humite minerals // Mineralogical Magazine. 2002. V. 66(3). P. 441–449.
Ribbe P.H., Gibbs G.V. Crystal Structures of the Humite Minerals: III. Mg/Fe Ordering in Humite and its Relation to Other Ferromagnesian Silicates // American Mineralogist. 1971. V. 56(7–8). P. 1155–1173.
Friedrich A., Lager G.A., Kunz M., Chakoumakos B.S., Smyth J.R., Schultz A.J. Temperature-dependent single-crystal neutron diffraction study of natural chondrodite and clinohumites // American Mineralogist. 2001. V. 86(9). P. 981–989.
Pekov I.V., Gerasimova E.I., Chukanov N.V., Kabalov Yu.K., Zubkova N.V., Zadov A.E., Yapaskurt V.O., Gekimyants V.M., Pushcharovskii D.Yu. Hydroxylchondrodite Mg5(SiO4)2(OH)2: A new mineral of the humite group and its crystal structure // Doklady Earth Sciences. 2011. V. 436. P. 230–236.
Ferraris G., Prencipe M., Sokolova E., Gekimyants V.M., Spiridonov E.M. Hydroxylclinohumite, a new member of the humite group: Twinning, crystal structure and crystal chemistry of the clinohumite subgroup // Zeitschrift für Kristallographie – Crystalline Materials. 2000. V. 215(3). P. 169–173.
Wunder B., Medenbach O., Daniels P., Schreyer W. First synthesis of the hydroxyl end-member of humite, Mg7Si3O12(OH)2 // American Mineralogist. 1995. V. 80. P. 638–640.
Redhammer G.J., Roth G., Amthauer G. Ca3GeO4Cl2 with a norbergite-like structure // Acta Cryst. 2007. C63. i69–i72.
Voron’ko Yu.K., Sobol’ A.A., Shukshin V.E., Zagumennyi A.I., Zavartsev Yu.D., Kutovoi S.A. Structural transformations in LiGd9(SiO4)6O2 and Ca2Gd8(SiO4)6O2 crystals containing isolated [SiO4] complexes: Raman spectroscopic study // Phys. Solid State. 2012. V. 54. P. 1635–1642.
Melcher C.L., Schweitzer J.S. Cerium-doped lutetium oxyorthosilicate: a fast, efficient new scintillator // IEEE Transactions on Nuclear Science. 1992. V. 39(4). P. 502–505.
Yu Ye, Smyth J.R., Jacobsen S.D., Céline G. Crystal chemistry, thermal expansion, and Raman spectra of hydroxyl-clinohumite: implications for water in Earth’s interior // Contributions to Mineralogy and Petrology. 2013. V. 165. P. 563–574.
Liu D., Pang Y., Yu Ye, Jin Z., Smyth J.R., Yang Y., Zhang Z., Wang Z. Crystal chemistry, thermal expansion, and Raman spectra of hydroxyl-clinohumite: implications for water in Earth’s interior // Contributions to Mineralogy and Petrology. 2013. V. 165. P. 563–574.
Sasaki A., Himeda A., Konaka H., Muroyama N. Ab initio crystal structure analysis based on powder diffraction data used PDXL // Rigaku J. 2010. V. 26. P. 10–14.
Bubnova R.S., Firsova V.A., Volkov S.N., Filatov S.K. RietveldToTensor: Program for Processing Powder X-Ray Diffraction Data under Variable Conditions // Glass Phys. Chem. 2018. V. 44. P. 33–40.
Momma K., Izumi F. VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data // J. Appl. Crystallogr. 2011. V. 44. P. 1272–1276.
Zulumyan N., Isahakyan A., Beglaryan H., Melikyan S. A study of thermal decomposition of antigorite from dunite and lizardite from peridotite // J. Therm. Anal. Calorim. 2018. V. 131. P. 1201–1211.
Бирюков Я.П., Бубнова Р.С., Филатов С.К., Гончаров А.Г. Синтез и термическое поведение оксобората Fe3O2(BO4) // Физика и химия стекла. 2016. Т. 42. С. 284–290.
Бирюков Я.П., Филатов С.К., Вагизов Ф.Г., Зинатуллин А.Л., Бубнова Р.С. Термическое расширение антиферромагнетиков FeBO3 и Fe3BO6 вблизи температуры Нееля // Журн. структурной химии. 2018. Т. 59. С. 2041–2048.
Бирюков Я.П., Бубнова Р.С., Дмитриева Н.В., Филатов С.К. Термическое поведение антиферромагнетиков FeBO3 и Fe3BO6 при отрицательных температурах // Физика и химия стекла. 2019. Т. 45. С. 184–188.
Филатов С.К. Обобщенная концепция повышения симметрии кристаллов с ростом температуры // Кристаллография. 2011. Т. 56(6). С. 1019–1028.