Synthesis and Characterization of Ceramics BaxMg(2 – x)F4 Activated by Tungsten

V. M. Lisitsyn; Лисицын В. М.; D. A. Musakhanov; Мусаханов Д. А.; T. G. Korzhneva; Коржнева Т. Г.; A. V. Strelkova; Стрелкова А. В.; L. A. Lisitsyna; Лисицына Л. А.; M. G. Golkovsky; Голковский М. Г.; A. M. Zhunusbekov; Жунусбеков А. М.; Zh. T. Karipbaev; Карипбаев Ж. Т.; A. L. Kozlovsky; Козловский А. Л.

doi:10.31857/S0132665122600169

Synthesis and Characterization of Ceramics BaxMg(2 – x)F4 Activated by Tungsten

Authors: Lisitsyn V.M.¹, Musakhanov D.A.², Korzhneva T.G.¹, Strelkova A.V.², Lisitsyna L.A.³, Golkovsky M.G.², Zhunusbekov A.M.², Karipbaev Z.T.², Kozlovsky A.L.²
Affiliations:
1. National Research Tomsk Polytechnic University
2. Gumilev Eurasian National University
3. Tomsk State University of Architecture and Building
Issue: Vol 49, No 3 (2023)
Pages: 323-329
Section: Articles
URL: https://rjmseer.com/0132-6651/article/view/663293
DOI: https://doi.org/10.31857/S0132665122600169
EDN: https://elibrary.ru/QDIMEM
ID: 663293

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

The possibility of radiation synthesis of luminescent ceramics from a mixture of Ba and Mg fluorides and WO3 oxide is shown for the first time. Synthesis is implemented in a powerful electron beam with an energy of 1.4 MeV by direct exposure of the charge to radiation. It is shown that the characteristic band is observed in the photoluminescence spectrum of the synthesized materials due to the introduction of tungsten, which indicates the incorporation of tungsten into the lattice during radiation synthesis without the use of additional substances in the charge.

Keywords

ceramics, metal fluorides, activator, radiation synthesis, structure, photoluminescence

References

Атрощенко Л.В., Бурачас С.Ф., Гальчинецкий Л.П., Гринев Б.В., Рыжиков В.Д., Старжинский Н.Г. Кристаллы, сцинтилляторы и детекторы ионизирующих излучений на их основе. Киев: Наук. думка, 1998. 310 с.
Kore B.P., Kumar A., Erasmus L., Kroon R.E., Terblans J.J., Dhoble S.J., Swart H.C. Energy Transfer Mechanisms and Optical Thermometry of BaMgF4: Yb3+, Er3+ Phosphor // Inorg. Chem. 2018. V. 57. № 1. P. 288−299.
Lisitsyna L.A., Lisitsyn V.M. Composition nanodefects in doped lithium fluoride crystals // Phys. Solid State. 2013. V. 55. № 11. P. 2297–2303.
Lisitsyn V.M., Golkovskii M.G., Lisitsyna L.A., Dauletbekova A.K., Musakhanov D.A., Vaganov V.A., Tulegenova A.T., Karipbayev Zh.T. MgF2 – Based Luminescing Ceramics // Russian Physics J. 2019. V. 61. № 10. P. 1908–1913.
Renfro G.M., Halliburton L.E., Sibley W.A., Belt R.F. Radiation effects in LiYF4 // J. Phys. C: Solid St. Phys. 1980. V. 13. № 10. P. 1941–1950.
Morato S.P., Masedo T.C.A. Fand photochromic centers in LiYF4:Nd crystals // Rad.eff. 1983. V. 72 № 2. P. 229–235.
Wang M., Mi C.C., Wang W.X., Liu C.H., Wu Y.F., Xu Z.R., Mao C.B., Xu S.K. Immunolabeling and NIR-excited fluorescent imaging of HeLa cells by using NaYF(4) : Yb,Er upconversion nanoparticles // ACS Nano. 2009. V. 3(6). P. 1580–1586.
Li Z.Q., Zhang Y., Jiang S. Synthesis of colour tunable lanthanide-ion doped NaYF4 upconversion nanoparticles by controlling temperature // Adv. Mater. 2008. V. 20. P. 4765.
Yagi K., Mori K., Odawara O., Wada H. Preparation of spherical upconversion nanoparticles NaYF4:Yb, Er by laser ablation in liquid and optical properties // J. Laser Appl. 2020. V. 32. 022062. https://doi.org/10.2351/7.0000089
Lisitsyn V.M., Golkovskii M.G., Lisitsyna L.A., Dauletbekova A.K., Musakhanov D.A., Vaganov V.A., Tulegenova A.T., Karipbayev Zh.T. MgF2–Based Luminescing Ceramics // Russian Physics J. 2019. V. 61. № 10. P. 1908–1913.
Gingl F. BaMgF4 and Ba2Mg3F10: new examples for structural relationships between hydrides and fluorides // Z. Anorg. Allg. Chem. 1997. V. 623. P. 705–709.