Synthesis and Crystal Structure of a Novel Organo-Inorganic Hybrid Borate, K[B5O6(OH)4][B(OH)3]2(H2O)(C10H20O5)2

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Abstract

Crystals of a novel hybrid organo-inorganic borate, K[B5O6(OH)4][B(OH)3]2(H2O)(C10H20O5)2 (1), were obtained from aqueous solutions and characterized by single-crystal X-ray diffraction and IR spectroscopy. 1 is triclinic (a = 10.1567(4), b = 11.9941(6), c = 17.1893(9) Å, α = 75.280(4), β = 79.406(4), γ = 88.531(4)°, V = 1990.270369 Å3, SG P-1; R1 = 0.058). Its structure contains [K(C10H20O5)2]+ groups which behave as “hydrophobic” templates for the inorganic part comprised of B5O6(OH)4 anions and neutral B(OH)3 molecules.

About the authors

V. A. Yukhno

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

Email: yukhno.valentina@gmail.com
Россия, 199034, Санкт-Петербург, наб. Макарова, 2

D. O. Charkin

Department of Chemistry, Moscow State University, 119991, Moscow, Russia; Laboratory of Arctic Mineralogy and Materials Sciences, Federal Research Center “Cola Science Center,” Russian Academy of Sciences, 184209, Apatity, Murmansk oblast, Russia

Email: yukhno.valentina@gmail.com
Россия, 119991, Москва, Ленинские горы, д. 1, стр. 3; Россия, 184209, Мурманская обл, Апатиты, ул. Ферсмана, 14

S. N. Volkov

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia; Laboratory of Arctic Mineralogy and Materials Sciences, Federal Research Center “Cola Science Center,” Russian Academy of Sciences, 184209, Apatity, Murmansk oblast, Russia

Email: yukhno.valentina@gmail.com
Россия, 199034, Санкт-Петербург, наб. Макарова, 2; Россия, 184209, Мурманская обл, Апатиты, ул. Ферсмана, 14

L. S. Manelis

Department of Chemistry, Moscow State University, 119991, Moscow, Russia; Laboratory of Arctic Mineralogy and Materials Sciences, Federal Research Center “Cola Science Center,” Russian Academy of Sciences, 184209, Apatity, Murmansk oblast, Russia

Email: yukhno.valentina@gmail.com
Россия, 119991, Москва, Ленинские горы, д. 1, стр. 3; Россия, 184209, Мурманская обл, Апатиты, ул. Ферсмана, 14

A. N. Gosteva

Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Federal Research Center “Cola Science Center,” Russian Academy of Sciences, 184209, Apatity, Murmansk oblast, Russia

Email: yukhno.valentina@gmail.com
Россия, 184209, Мурманская обл.,, Апатиты, мкр. Академгородок, д. 26А

S. M. Aksenov

Laboratory of Arctic Mineralogy and Materials Sciences, Federal Research Center “Cola Science Center,” Russian Academy of Sciences, 184209, Apatity, Murmansk oblast, Russia

Email: yukhno.valentina@gmail.com
Россия, 184209, Мурманская обл, Апатиты, ул. Ферсмана, 14

R S. Bubnova

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

Author for correspondence.
Email: rimma_bubnova@mail.ru
Россия, 199034, Санкт-Петербург, наб. Макарова, 2

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Copyright (c) 2023 В.А. Юхно, Д.О. Чаркин, С.Н. Волков, Л.С. Манелис, А.Н. Гостева, С.М. Аксенов, Р.С. Бубнова