Synthesis and Structure of New Potassium and Cesium Zinc Diphosphates

D. I. Tsygankova; Цыганкова Д. И.; O. Yu. Sinel’shchikova; Синельщикова О. Ю.; V. L. Ugolkov; Уголков В. Л.

doi:10.31857/S0132665123600322

Synthesis and Structure of New Potassium and Cesium Zinc Diphosphates

Authors: Tsygankova D.I.¹^,2, Sinel’shchikova O.Y.¹, Ugolkov V.L.¹
Affiliations:
1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia
2. Ulyanov (Lenin) St. Petersburg State Electrotechnical University “LETI,”, 197022, St. Petersburg, Russia
Issue: Vol 49, No 6 (2023)
Pages: 642-650
Section: Articles
URL: https://rjmseer.com/0132-6651/article/view/663359
DOI: https://doi.org/10.31857/S0132665123600322
EDN: https://elibrary.ru/EMTKNK
ID: 663359

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Abstract

This article presents the results of a study of new solid solutions formed in the system of diphosphates of alkaline elements and zinc: K2Zn3(P2O7)2–Cs2Zn3(P2O7)2. The obtained materials are promising as matrices for creating phosphors. The formation of phases containing two alkali cations is established on samples obtained by solid-phase synthesis by X-ray phase analysis, and the results of studying their thermal stability are presented.

Keywords

solid-phase synthesis, alkali metal diphosphates, solid solutions

About the authors

D. I. Tsygankova

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia; Ulyanov (Lenin) St. Petersburg State Electrotechnical University “LETI,”, 197022, St. Petersburg, Russia

Email: sinelshikova@mail.com
Россия, 199034, Санкт-Петербург, наб. Макарова, д. 2; Россия, 197022, Санкт-Петербург, ул. Профессора Попова, д. 5

O. Yu. Sinel’shchikova

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

Email: sinelshikova@mail.com
Россия, 199034, Санкт-Петербург, наб. Макарова, д. 2

V. L. Ugolkov

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

Author for correspondence.
Email: sinelshikova@mail.com
Россия, 199034, Санкт-Петербург, наб. Макарова, д. 2

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