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Reaction of Hydrogen Sulfide with a Chlorine Atom in the Temperature Range of 273 to 366 K
- Authors: Larin I.K.1, Belyakova T.I.1, Messineva N.A.1, Trofimova E.M.1
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Affiliations:
- Talrose Institute for Energy Problems of Chemical Physic, Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
- Issue: Vol 42, No 4 (2023)
- Pages: 89-94
- Section: Химическая физика атмосферных явлений
- URL: https://rjmseer.com/0207-401X/article/view/674883
- DOI: https://doi.org/10.31857/S0207401X23040118
- EDN: https://elibrary.ru/MXGZMS
- ID: 674883
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Abstract
The method of resonance fluorescence (RF) of chlorine atoms in a flow reactor in the temperature range of 273 to 366 K is used to measure the rate constant of the reactions of a chlorine atom with hydrogen sulfide, the value of which decreased as temperature in the reactor increased. This behavior of the rate constant could be explained by the fact that this reaction occurs on the surface of the reactor. However, experiments carried out under different conditions of the diffusion of reagents to the surface of the reactor showed that the reaction of the chlorine atom with hydrogen sulfide proceeds in the volume.
About the authors
I. K. Larin
Talrose Institute for Energy Problems of Chemical Physic, Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
Email: eltrofimova@yandex.ru
Moscow, Russia
T. I. Belyakova
Talrose Institute for Energy Problems of Chemical Physic, Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
Email: eltrofimova@yandex.ru
Moscow, Russia
N. A. Messineva
Talrose Institute for Energy Problems of Chemical Physic, Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
Email: nat-messineva@yandex.ru
Moscow, Russia
E. M. Trofimova
Talrose Institute for Energy Problems of Chemical Physic, Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
Author for correspondence.
Email: eltrofimova@yandex.ru
Moscow, Russia
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