Absorption of Sulfur During Filtration Combustion of Sulfur-Containing Solid Fuels and Waste by Calcium-Containing Sorbents

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Abstract

The analysis of the results of studies on the absorption of sulfur using marble additives in the charge during filtration combustion of various types of sulfur fuels and waste was carried out. It has been shown that when fuels containing metal sulfides and organic sulfur compounds are burned, the addition of marble can significantly (2–3 times) increase the proportion of sulfur passing into solid combustion products, whereas for fuels containing metal sulfates, a similar addition of marble increases the sulfur content in the solid residue by only 25–30%.

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About the authors

V. M. Kislov

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences

Author for correspondence.
Email: vmkislov@icp.ac.ru
Russian Federation, Chernogolovka

Yu. Yu. Tsvetkova

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences

Email: vmkislov@icp.ac.ru
Russian Federation, Chernogolovka

E. N. Pilipenko

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences

Email: vmkislov@icp.ac.ru
Russian Federation, Chernogolovka

M. V. Salganskaya

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences

Email: vmkislov@icp.ac.ru
Russian Federation, Chernogolovka

A. Yu. Zaychenko

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences

Email: vmkislov@icp.ac.ru
Russian Federation, Chernogolovka

D. N. Podlesny

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences

Email: vmkislov@icp.ac.ru
Russian Federation, Chernogolovka

E. A. Salgansky

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences

Email: vmkislov@icp.ac.ru
Russian Federation, Chernogolovka

M. V. Tsvetkov

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences

Email: vmkislov@icp.ac.ru
Russian Federation, Chernogolovka

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2. Fig. 1. Change in the elemental composition of coal during oxidation: relative change in the fraction (N) of carbon (1), hydrogen (2), oxygen (3), sulphur (4) and nitrogen (5).

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3. Fig. 2. Dependence of change in mass of marble particles residue on the calcination temperature: 1 - marble particles loaded into the furnace in their original form (without coal); 2 - coal and marble particles loaded layer by layer into the cuvette; 3 - mass of marble during calcination with coal, calculated on the basis of the chemical composition of the samples obtained in the experiment, assuming that the formed products are CaO and CaS.

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4. Fig. 3. Change in time of sulphur content during calcination of brown coal and marble in the resulting products: 1 - in solid coal residue, 2 - in marble, 3 - in gaseous products.

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