Reaction of 4,6-di-tert-butyl-3-nitrocyclohex-3,5-diene1,2-dione with secondary amines

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Abstract

Reaction of 4,6-di- tert -butyl-3-nitrocyclohexa-3,5-diene-1,2-dione with secondary amines (piperidine, morpholine, 1-methylpiperazine) in isopropanol leads to a mixture of products formed as a result of parallel reactions of Michael addition and ANRORC. The compounds obtained were characterized by 1H NMR, 13C NMR, IR spectroscopy, and elemental analysis. Molecular structure of 3-nitrocyclohexa-3-ene-1,2-dione and cyclopenta1,3-diene derivatives was established by X-ray diffraction analysis.

About the authors

E. P. Ivakhnenko

Institute of Physical and Organic Chemistry, Southern Federal University

Email: ivakhnenko@sfedu.ru

V. I. Malay

Institute of Physical and Organic Chemistry, Southern Federal University

O. P. Demidov

North Caucasus Federal University

Email: odemidov@gmail.com

V. I. Minkin

Institute of Physical and Organic Chemistry, Southern Federal University

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