Addition of Diols to 2-Methylene-1,4-dioxaspiro[4.5]decane

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Authors: Borisova Y.G.¹, Sokov S.A.¹, Golovanov A.A.¹, Raskildina G.Z.¹, Zlotsky S.S.¹
Affiliations:
1. Ufa State Petroleum Technical University
Issue: Vol 61, No 1 (2025)
Pages: 115-118
Section: КРАТКОЕ СООБЩЕНИЕ
URL: https://rjmseer.com/0514-7492/article/view/682066
DOI: https://doi.org/10.31857/S0514749225010104
EDN: https://elibrary.ru/AFFLKI
ID: 682066

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Abstract

A method has been developed for the electrophilic addition of 1,2-, 1,3- and 1,4-diols to 4-methylene-1,3-dioxolane under trifluoroacetic acid catalysis. Conditions for the predominant formation of mono-adducts with yields of 31–70% were selected.

Keywords

2-methylene-1,4-dioxaspiro[4.5]decane, catalysis, trifluoroacetic acid, electrophilic addition, cyclic acetals, glycols

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About the authors

Yu. G. Borisova

Ufa State Petroleum Technical University

Author for correspondence.
Email: yulianna_borisova@mail.ru
ORCID iD: 0000-0001-6452-9454
Russian Federation, 1, Cosmonaut Ave., Ufa, 450064

S. A. Sokov

Ufa State Petroleum Technical University

Email: yulianna_borisova@mail.ru
ORCID iD: 0000-0002-0639-0455
Russian Federation, 1, Cosmonaut Ave., Ufa, 450064

A. A. Golovanov

Ufa State Petroleum Technical University

Email: yulianna_borisova@mail.ru
ORCID iD: 0000-0001-7133-3070
Russian Federation, 1, Cosmonaut Ave., Ufa, 450064

G. Z. Raskildina

Ufa State Petroleum Technical University

Email: yulianna_borisova@mail.ru
ORCID iD: 0000-0001-9770-5434
Russian Federation, 1, Cosmonaut Ave., Ufa, 450064

S. S. Zlotsky

Ufa State Petroleum Technical University

Email: yulianna_borisova@mail.ru
ORCID iD: 0000-0001-6365-5010
Russian Federation, 1, Cosmonaut Ave., Ufa, 450064

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