Plasma Spraying of Silicide Coatings to Protect Zirconium Alloys from Oxidation

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Abstract

The work is devoted to an experimental study of the possibilities of applying a protective silicide coating on an alloy based on zirconium (E110) by atmospheric plasma spraying. Coatings based on the binary eutectic Mo5Si3 + MoSi2 were deposited on the surface of E110 alloy sheet. The features of the structure and phase composition of the coatings after deposition and their evolution as a result of isothermal annealing at a temperature of 1300°C are studied. Upon rapid cooling of silicide particles during coating, nonequilibrium phases are formed. As a result of annealing, the phase composition changes, which corresponds to the phase diagram. The kinetics of diffusion interaction between the coating and the base material has been studied. The possibility of successfully protecting a zirconium alloy from oxidation at 1100°C in air by complex deposition of a coating of molybdenum silicides has been shown for the first time. The minimum radius of curvature of the surface of the protected samples was about 1 mm.

About the authors

I. B. Gnesin

Institute of Solid State Physics RAS

Author for correspondence.
Email: ibgnesin@issp.ac.ru
Russia, 142432, Chernogolovka

D. V. Prokhorov

Institute of Solid State Physics RAS

Email: ibgnesin@issp.ac.ru
Russia, 142432, Chernogolovka

N. I. Gnesina

Institute of Solid State Physics RAS

Email: ibgnesin@issp.ac.ru
Russia, 142432, Chernogolovka

A. N. Nekrasov

Institute of Experimental Mineralogy RAS

Email: ibgnesin@issp.ac.ru
Russia, 142432, Chernogolovka

B. A. Gnesin

Institute of Solid State Physics RAS

Email: ibgnesin@issp.ac.ru
Russia, 142432, Chernogolovka

V. I. Vnukov

Institute of Solid State Physics RAS

Email: ibgnesin@issp.ac.ru
Russia, 142432, Chernogolovka

M. I. Karpov

Institute of Solid State Physics RAS

Email: ibgnesin@issp.ac.ru
Russia, 142432, Chernogolovka

I. S. Zheltyakova

Institute of Solid State Physics RAS

Email: ibgnesin@issp.ac.ru
Russia, 142432, Chernogolovka

T. S. Stroganova

Institute of Solid State Physics RAS

Email: ibgnesin@issp.ac.ru
Russia, 142432, Chernogolovka

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Copyright (c) 2023 И.Б. Гнесин, Д.В. Прохоров, Н.И. Гнесина, А.Н. Некрасов, Б.А. Гнесин, В.И. Внуков, М.И. Карпов, И.С. Желтякова, Т.С. Строганова