Effect of Phosphorus-Containing Dispersant on the Microstructure and Optical Properties of Scintillation Ceramic (Gd, Y)3(Al, Ga)5O12:Ce with Garnet Structure

P. V. Karpyuk; Карпюк П. В.; L. V. Ermakova; Ермакова Л. В.; V. V. Dubov; Дубов В. В.; D. E. Lelekova; Лелекова Д. Е.; R. R. Saifutyarov; Сайфутяров Р. Р.; P. A. Zhdanov; Жданов П. А.; M. S. Malozovskaya; Малозовская М. С.; I. Y. Komendo; Комендо И. Ю.; P. S. Sokolov; Соколов П. С.; A. G. Bondarau; Бондарев А. Г.; M. V. Korzhik; Коржик М. В.

doi:10.31857/S1028096024080156

Effect of Phosphorus-Containing Dispersant on the Microstructure and Optical Properties of Scintillation Ceramic (Gd, Y)3(Al, Ga)5O12:Ce with Garnet Structure

Authors: Karpyuk P.V.¹, Ermakova L.V.¹, Dubov V.V.¹, Lelekova D.E.¹, Saifutyarov R.R.¹, Zhdanov P.A.¹, Malozovskaya M.S.¹, Komendo I.Y.¹, Sokolov P.S.¹, Bondarau A.G.², Korzhik M.V.²
Affiliations:
1. National Research Center “Kurchatov Institute”
2. Institute for Nuclear Problems, Belarus State University
Issue: No 8 (2024)
Pages: 123-132
Section: Articles
URL: https://rjmseer.com/1028-0960/article/view/664770
DOI: https://doi.org/10.31857/S1028096024080156
EDN: https://elibrary.ru/EKLKIP
ID: 664770

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Abstract

Phosphoric acid ester, a typical component of commercial dispersants, affects the functional properties of Gd_1.494Y_1.494Ce_0.012Al₂Ga₃O₁₂ ceramics. In sintered ceramics, the residual phosphorus can reach up to 40–70% of the introduced amount. The admixture of phosphorus located on the surfaces of the particles activates the grain growth during sintering and leads to the formation of secondary phases of rare-earth phosphates. With increasing phosphorus concentration, the density and optical transmittance of ceramics decrease. Relatively small amount of phosphorus can improve the luminescence properties of ceramics, but large amounts can increase phosphorescence and reduce the scintillation light yield.

Keywords

garnet, ceramics, scintillator, 3D printing, phosphoric acid ester

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No 1 (2025)

Effect of Phosphorus-Containing Dispersant on the Microstructure and Optical Properties of Scintillation Ceramic (Gd, Y)3(Al, Ga)5O12:Ce with Garnet Structure

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Abstract

Keywords

About the authors

P. V. Karpyuk

L. V. Ermakova

V. V. Dubov

D. E. Lelekova

R. R. Saifutyarov

P. A. Zhdanov

M. S. Malozovskaya

I. Y. Komendo

P. S. Sokolov

A. G. Bondarau

M. V. Korzhik

References

Supplementary files